Manipal Medical Manipal Medical Solved Paper-2014

  • question_answer
    A solution containing equimolar amounts of \[NiC{{l}_{2}}\] and \[SnB{{r}_{2}}\] is electrolysed using a 9V battery and graphite electrodes. What are the first products formed?
    Half reaction Standard reduction potential (V)
    \[N{{i}^{2+}}(aq)+2{{e}^{-}}\to Ni(s)\] - 0.236
    \[S{{n}^{2+}}(aq)+2{{e}^{-}}\to Sn(s)\] - 0.141
    \[B{{r}_{2}}(aq)+2{{e}^{-}}\to 2B{{r}^{-}}(aq)\] 1.077
    \[C{{l}_{2}}(aq)+2{{e}^{-}}\to 2C{{l}^{-}}(aq)\] 1.360
     

    A) Ni (s) at cathode, \[C{{l}_{2}}\](aq) at anode

    B) Ni (s) at cathode, \[B{{r}_{2}}\] (aq) at anode

    C) Sn (s) at cathode, \[B{{r}_{2}}\] (aq) at anode

    D) Sn (s) at cathode, \[C{{l}_{2}}\] (aq) at anode

    Correct Answer: C

    Solution :

    Metal with higher reduction potential (here Sn)    will be first deposited at cathode and anion with higher oxidation potential (here\[B{{r}^{-}}\]) will be oxidised at anode.


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