Manipal Medical Manipal Medical Solved Paper-2015

  • question_answer
    1 mole of \[MnO_{4}^{2-}\]in neutral aqueous medium disproportionate to

    A) \[\frac{2}{3}\]mole of \[MnO_{4}^{-}\] and \[\frac{1}{3}\] mole of \[Mn{{O}_{2}}\]

    B) \[\frac{1}{3}\] mole of \[MnO_{4}^{-}\] and \[\frac{2}{3}\] mole of \[Mn{{O}_{2}}\]

    C) \[\frac{1}{2}\]mole of \[M{{n}_{2}}{{O}_{7}}\] and \[\frac{1}{3}\] mole of \[Mn{{O}_{2}}\]

    D) \[\frac{2}{3}\] mole of \[M{{n}_{2}}{{O}_{7}}\] and \[\frac{1}{3}\]mole of \[Mn{{O}_{2}}\]                                                               

    Correct Answer: A

    Solution :

    \[M{{n}^{6+}}\to M{{n}^{7+}}+1{{e}^{-}}\]                 \[M{{n}^{6+}}+2{{e}^{-}}\to M{{n}^{4+}}\] \[\therefore \]   \[3MnO_{4}^{2-}\to 2MnO_{4}^{-}+Mn{{O}_{2}}\]


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