A) \[C{{H}_{3}}-\underset{\begin{smallmatrix} | \\ C{{H}_{3}} \end{smallmatrix}}{\overset{\begin{smallmatrix} OH \\ | \end{smallmatrix}}{\mathop{C}}}\,-C{{H}_{3}}\]
B) \[C{{H}_{3}}-\overset{\begin{smallmatrix} OH \\ | \end{smallmatrix}}{\mathop{CH}}\,-C{{H}_{3}}\]
C) \[{{(C{{H}_{3}})}_{3}}-C-C{{H}_{2}}OH\]
D) none of the above
Correct Answer: B
Solution :
Only\[1{}^\circ \]alochol and\[2{}^\circ \]alcohol react with alkaline\[KMn{{O}_{4}}\]. \[\underset{Alcohol}{\mathop{C{{H}_{3}}.\overset{\begin{smallmatrix} OH \\ | \end{smallmatrix}}{\mathop{CH}}\,.C{{H}_{3}}}}\,\xrightarrow[{}]{KMn{{O}_{4}}}\underset{Ketone}{\mathop{C{{H}_{3}}.\overset{\begin{smallmatrix} O \\ || \end{smallmatrix}}{\mathop{C}}\,.C{{H}_{3}}}}\,\] \[\xrightarrow[{}]{[O]}\underset{Ketone}{\mathop{C{{H}_{3}}COOH}}\,\]
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