A) \[r=k{{[{{O}_{3}}]}^{2}}\]
B) \[r=k{{[{{O}_{3}}]}^{2}}{{[{{O}_{2}}]}^{-1}}\]
C) \[r=k[{{O}_{3}}][{{O}_{2}}]\]
D) None of these
Correct Answer: B
Solution :
\[{{K}_{eq}}=\frac{[O][{{O}_{2}}]}{[{{O}_{3}}]}\] (form (i) Eq.) \[[O]=\frac{{{K}_{eq}}[{{O}_{3}}]}{[{{O}_{2}}]}\] Rate law, \[r=k[{{O}_{3}}][O]\] (from (ii) Eq.) \[r=\frac{k[{{O}_{3}}][{{O}_{3}}]}{[{{O}_{2}}]}{{K}_{eq}}\] \[r=k'{{[{{o}_{3}}]}^{2}}{{[{{O}_{2}}]}^{-1}}\] \[[\because k.{{K}_{eq}}=k']\]
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