MGIMS WARDHA MGIMS WARDHA Solved Paper-2011

  • question_answer
    \[C{{H}_{3}}CHO+C{{H}_{3}}CHO\xrightarrow{Dil.O{{H}^{-}}}\]\[C{{H}_{3}}CH(OH)C{{H}_{2}}CHO,\]the intermediate in the above reaction is

    A)  carbanion          

    B)  carbonium ion

    C)   carbene            

    D)  None of these

    Correct Answer: A

    Solution :

                     The given reaction is called the aldol condensation and involves the following steps. \[C{{H}_{3}}CHO\xrightarrow[{}]{Dil,.O{{H}^{-}}}\underset{carbainion}{\mathop{\overset{O-}{\mathop{C}}\,{{H}_{2}}CHO}}\,\overset{{}}{\longleftrightarrow}C{{H}_{2}}=CH-{{O}^{-}}\]


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