MGIMS WARDHA MGIMS WARDHA Solved Paper-2011

  • question_answer
    For the reaction,\[{{N}_{2}}+3{{H}_{2}}2N{{H}_{3}};\]     \[\Delta H=?\]

    A) \[\Delta E+2RT\]              

    B) \[\Delta F-2RT\]

    C)   \[\Delta F+RT\]              

    D) \[\Delta E-RT\]

    Correct Answer: B

    Solution :

                     \[{{N}_{2}}+3{{H}_{2}}2N{{H}_{3}}\] \[\Delta H=\Delta E+\Delta {{n}_{g}}RT\] \[\Delta {{n}_{g}}={{n}_{p}}-{{n}_{r}}=2-4=-2\]  \[\therefore \]  \[\Delta H=\Delta E+(-2)RT\]                 \[\Delta H=\Delta E-2RT\]


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