NEET Chemistry Chemical Bonding and Molecular Structure / रासायनिक आबंधन एवं आणविक संरचना NEET PYQ-Chemical Bonding Molecular

  • question_answer
    According to MO theory which of the following lists ranks the nitrogen species in tends of increasing bond order?       [AIPMT (S) 2009]

    A)  \[\underset{\begin{smallmatrix}  \text{ }\!\!|\!\!\text{ } \\  \text{H} \end{smallmatrix}}{\overset{\begin{smallmatrix}  \text{H} \\  \text{ }\!\!|\!\!\text{ } \end{smallmatrix}}{\mathop{\text{C}}}}\,=\underset{\begin{smallmatrix}  \text{ }\!\!|\!\!\text{ } \\  \text{H} \end{smallmatrix}}{\overset{\begin{smallmatrix}  \text{H} \\  \text{ }\!\!|\!\!\text{ } \end{smallmatrix}}{\mathop{\text{C}}}}\,+\text{H}-\xrightarrow[{}]{{}}\text{H}-\underset{\begin{smallmatrix}  \text{ }\!\!|\!\!\text{ } \\  \text{H} \end{smallmatrix}}{\overset{\begin{smallmatrix}  \text{H} \\  \text{ }\!\!|\!\!\text{ } \end{smallmatrix}}{\mathop{\text{C}}}}\,-\underset{\begin{smallmatrix}  \text{ }\!\!|\!\!\text{ } \\  \text{H} \end{smallmatrix}}{\overset{\begin{smallmatrix}  \text{H} \\  \text{ }\!\!|\!\!\text{ } \end{smallmatrix}}{\mathop{\text{C}}}}\,-\text{H}\]

    B)       \[\text{mo}{{\text{l}}^{\text{-1}}}\]

    C)  \[\text{mo}{{\text{l}}^{\text{-1}}}\]

    D)       \[\text{mo}{{\text{l}}^{\text{-1}}}\]

    Correct Answer: B

    Solution :

    Key Idea Bond order \[{{B}_{2}}{{O}_{3}}\] where,
    \[CaO\] number of electrons in bonding MO
    \[Si{{O}_{2}}\] number of electrons in anti bonding MO
    \[BeO\]
    \[{{[Co{{(en)}_{2}}C{{l}_{2}}]}^{+}}\]
    \[{{[Co{{(N{{H}_{3}})}_{3}}C{{l}_{3}}]}^{0}}\]
    \[{{[Co(en)C{{l}_{2}}{{(N{{H}_{3}})}_{2}}]}^{+}}\]
    \[{{[Co{{(en)}_{3}}]}^{3+}}\]
    \[A{{l}_{2}}{{O}_{3}}\]
    \[4.5\times {{10}^{4}}\]
    \[A{{l}_{2}}{{O}_{3}}\]
    \[\text{A}l=27\text{g}\,\text{mo}{{\text{l}}^{-1}}\]
    \[9.0\times {{10}^{3}}g\]\[8.1\times {{10}^{4}}g\]
    Hence, the increasing order of B.O is,
    \[2.4\times {{10}^{5}}g\]


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