A) In \[K\,vsT\]
B) \[\frac{\text{ln}K}{T}vsT\]
C) In \[Kvs\frac{l}{T}\]
D) \[\frac{T}{\ln \,k}vs\frac{l}{T}\]
Correct Answer: C
Solution :
[c] By Arrhenius equation |
\[K=A{{e}^{-{{E}_{a}}/RT}}\] |
where, \[{{E}_{a}}\] = energy of activation |
Applying log on both the side, |
\[\ln \,k=\ln A-\frac{{{E}_{a}}}{RT}\,\,\,\,\,\,\,\] (i) |
or\[\log \,k=-\frac{{{E}_{a}}}{2.303RT}+\log A\,\] (ii) |
This equation is of the form of \[y=mx+c\] i.e. the equation of a straight line. Thus, if a plote of \[\log k\,vs\frac{1}{T}\] is a straight line, the validity of the equation is confirmed. |
Slope of the line \[=-\frac{{{E}_{a}}}{2.303R}\] |
Thus, measuring the slope of the line, the value of \[{{E}_{a}}\] can be calculated. |
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