NEET Chemistry Concepts of Acids & Bases NEET PYQ-Concepts Of Acids Bases

  • question_answer
    Which of the following order is wrong?                                                                   [AIPMT 2002]

    A)        \[N{{H}_{3}}<\text{ }P{{H}_{3}}<\text{ }As{{H}_{3}}\]acidic

    B)                   \[Li<Be<B<C-\]1st IP

    C)  \[A{{I}_{2}}{{O}_{3}}<MgO<N{{a}_{2}}O<{{K}_{2}}O\]basic

    D)       \[L{{i}^{+}}<N{{a}^{+}}<{{K}^{+}}<C{{s}^{+}}-\]ionic radius

    Correct Answer: B

    Solution :

    Li, Be, B and C are present in IInd period. In a period from left to right ionisarion potential increases.
    \[\underset{Li\,\,\,Be\,\,B\,\,C}{\mathop{\xrightarrow{IP\,increases}}}\,\]
                * But in case of Be and B, Be has higher IP than B due to stable configuration of Be
                            \[_{4}Be=1{{s}^{2}},\,2{{s}^{2}}\]   \[\underset{2{{s}^{2}}}{\mathop{}}\,\,\,\text{stable configuration}\]
    \[_{5}B=1{{s}^{2}},\,2{{s}^{2}}\,2{{p}^{1}}\]\[\underset{2{{p}^{1}}}{\mathop{}}\,\text{ unstable configuration}\]
    So, the correct order of IP of given elements is
    \[Li<B<Be<C\]


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