NEET Chemistry NEET PYQ-Coordination Chemistry

  • question_answer
    Which of the following has longest C-O bond length? (Free C-O bond length in Co is\[1.128\overset{\text{o}}{\mathop{\text{A}}}\,\]). [NEET - 2016]

    A) \[Ni{{(CO)}_{4}}\]

    B) \[{{[Co{{(CO)}_{4}}]}^{\text{O}-}}\]

    C) \[{{[Fe{{(CO)}_{4}}]}^{2-}}\] 

    D) \[{{[Mn{{(CO)}_{6}}]}^{+}}\]

    Correct Answer: C

    Solution :

    [c] \[{{[Fe{{(CO)}_{4}}]}^{2-}}\]
    Since metal atom is carrying maximum -ve charge therefore it would show maximum synergic bonding as sa resultant C-O bond length would be maximum.


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