NEET Chemistry NEET PYQ-The d-and f-Block Elements

  • question_answer
    The catalytic activity of transition metals and their compounds is ascribed mainly to [AIPMT (M) 2012]

    A) their magnetic behavior

    B) their unfilled d-orbitals

    C) their ability to adopt variable oxidation states

    D) their chemical reactivity

    Correct Answer: C

    Solution :

    [c] Transition metals show variable oxidation states, due to which they can perform as catalyst.
                e.g.,      \[2S{{O}_{2}}+{{O}_{2}}\xrightarrow[(catalyst)]{{{V}_{2}}{{O}_{5}}}2S{{O}_{3}}\]
                \[S{{O}_{2}}+{{\overset{+5}{\mathop{V}}\,}_{2}}{{O}_{5}}\xrightarrow{{}}S{{O}_{3}}+{{\overset{+4}{\mathop{V}}\,}_{2}}{{O}_{4}}\]
                \[{{\overset{+4}{\mathop{V}}\,}_{2}}{{O}_{4}}+{{O}_{2}}\xrightarrow{{}}{{\overset{+5}{\mathop{V}}\,}_{2}}{{O}_{5}}\]


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