NEET Chemistry NEET PYQ-The d-and f-Block Elements

  • question_answer
    Which one of the following ions exhibits d-d transition and paramagnetism as well? [NEET - 2018]

    A) \[\text{MnO}_{\text{4}}^{\text{-}}\]

    B) \[\text{C}{{\text{r}}_{\text{2}}}\text{O}_{\text{7}}^{\text{2-}}\]

    C) \[\text{CrO}_{4}^{\text{2-}}\]

    D) \[\text{MnO}_{\text{4}}^{\text{2-}}\]

    Correct Answer: D

    Solution :

    [d] \[\text{CrO}_{4}^{2-}\Rightarrow C{{r}^{6+}}=[Ar]\]
    Unpaired electron \[\text{(n)=0;}\] Diamagnetic
    \[\text{C}{{\text{r}}_{2}}O_{7}^{2-}\Rightarrow C{{r}^{6+}}=[Ar]\]
    Unpaired electron \[\text{(n)=0}\]; Diamagnetic
    \[\text{MnO}_{4}^{2-}=M{{n}^{6+}}=[Ar]3{{d}^{1}}\]
    Unpaired electron \[(n)=1\]; Paramagnetic
    \[MnO_{4}^{-}=M{{n}^{7+}}=[Ar]\]
    Unpaired electron \[(n)\text{ }=\text{ }0;\] Diamagnetic


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