NEET Chemistry NEET PYQ-The d-and f-Block Elements

  • question_answer
    Which one of the following forms a colourless solution in aqueous medium?     [AIPMT 2000]
    (Atomic number  :\[Sc=21,\text{ }Ti=22,\text{ }V=23,\text{ }Cr=24\])

    A) \[{{V}^{3+}}\]

    B) \[C{{r}^{3+}}\]

    C) \[T{{i}^{3+}}\]

    D) \[S{{c}^{3+}}\]

    Correct Answer: D

    Solution :

    [d] The electronic configuration of Sc is
                \[1{{s}^{2}},\text{ }2{{s}^{2}}2{{p}^{6}},\text{ }3{{s}^{2}}3{{p}^{6}}3{{d}^{1}},\text{ }4{{s}^{2}}\]
                and configuration of  \[S{{c}^{3+}}\] is
                \[1{{s}^{2}},\text{ }2{{s}^{2}}2{{p}^{6}},\text{ }3{{s}^{2}}3{{p}^{6}}\]
                            So, \[S{{c}^{3+}}\] is colourless due to absence of unpaired electrons in d-orbital.
               


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