NEET Chemistry NEET PYQ-The Solid State

  • question_answer
    If NaCl is doped with \[{{10}^{-4}}mol\text{ }%\] of \[SrC{{l}_{2}},\] the concentration of cation vacancies will be \[({{N}_{A}}=6.02\times {{10}^{23}}mo{{l}^{-1}})\]:                [AIPMT (S) 2007]

    A) \[6.02\times {{10}^{15}}mo{{l}^{-1}}\]

    B) \[6.02\times {{10}^{16}}mo{{l}^{-1}}\]

    C) \[6.02\times {{10}^{17}}mo{{l}^{-1}}\]

    D) \[6.02\times {{10}^{14}}mo{{l}^{-1}}\]

    Correct Answer: A

    Solution :

    [a] If \[NaCl\,(N{{a}^{+}})\] is doped with \[{{10}^{-4}}\] mol % of \[SrC{{l}_{2}}\,(S{{r}^{2+}})\]
                \[2N{{a}^{+}}\] ion doped by \[S{{r}^{2+}}\,{{N}_{A}}=6.02\times {{10}^{23}}\]
                The concentration of cation vacancies =
                \[=6.02\times {{10}^{23}}\times {{10}^{-8}}\]
                \[=6.02\times {{10}^{15}}\,mo{{l}^{-1}}\]


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