Equilibrium constants \[{{K}_{1}}\] and \[{{K}_{2}}\] for the following equilibria: |
\[{{N}_{2}}(g)+\frac{1}{2}{{O}_{2}}\,N{{O}_{2}}(g)\,\] and |
\[2N{{O}_{2}}(g)\,2NO(g)+{{O}_{2}}(g)\] |
are related as: [AIPMT (S) 2005] |
A) \[{{K}_{2}}=\frac{1}{{{K}_{1}}}\]
B) \[{{K}_{2}}=K_{1}^{2}\]
C) \[{{K}_{2}}=\frac{{{K}_{1}}}{2}\]
D) \[{{K}_{2}}=\frac{1}{K_{1}^{2}}\]
Correct Answer: D
Solution :
(i) |
(ii) |
From eq. (i) |
From Eqs. (ii) and (iii) |
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