Punjab Medical Punjab - MET Solved Paper-2011

  • question_answer
    \[C{{H}_{3}}COOH\]is reacted with\[CH\equiv CH\]in presence of\[H{{g}^{2+}}\]the product is

    A) \[\underset{\begin{smallmatrix}  | \\  C{{H}_{2}} \end{smallmatrix}}{\mathop{C{{H}_{2}}}}\,(OOC{{H}_{3}})\]

    B) \[\underset{\begin{smallmatrix}  | \\  C{{H}_{2}}-(OOC-C{{H}_{3}}) \end{smallmatrix}}{\mathop{C{{H}_{3}}}}\,\]

    C) \[{{\underset{\begin{smallmatrix}  | \\  CH-(OOC-C{{H}_{3}}) \end{smallmatrix}}{\mathop{C{{H}_{3}}}}\,}_{2}}\]

    D)  None of the above

    Correct Answer: C

    Solution :

    \[CH\equiv CH+C{{H}_{3}}COOH\xrightarrow{(H{{g}^{2+}})}\]\[{{H}_{2}}\underset{vinylacetate}{\mathop{G=CH-}}\,OCOC{{H}_{3}}\] \[\xrightarrow{C{{H}_{3}}COOH}C{{H}_{3}}\underset{ethylidene\,\,acetate}{\mathop{-CH(O-}}\,COC{{H}_{3}}{{)}_{2}}\]


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