RAJASTHAN ­ PET Rajasthan PET Solved Paper-2003

  • question_answer
    Which of the following is formed on the hydrolysis of product, formed by the reaction of\[C{{H}_{3}}CHO\]and\[C{{H}_{3}}MgBr\]?

    A)  Primary alcohol  

    B)  Secondary alcohol

    C)  Tertiary alcohol  

    D)  Ketone

    Correct Answer: B

    Solution :

     \[\underset{acetaldehyde}{\mathop{C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\mathop{C}}\,=O}}\,+\underset{\begin{smallmatrix}  Grignard's \\  reagent \end{smallmatrix}}{\mathop{C{{H}_{3}}MgBr}}\,\xrightarrow[{}]{{}}\] \[C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C}}}\,-OMgBr\xrightarrow[{}]{{{H}_{2}}O}\underset{secondary\text{ }alcohol}{\mathop{C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C}}}\,-OH}}\,\]


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