RAJASTHAN ­ PET Rajasthan PET Solved Paper-2003

  • question_answer
    At\[300{}^\circ C,\]the vapour density of\[PC{{l}_{5}}\]is 60. At this temperature, its dissociation percentage will be

    A)  73                

    B)  77

    C)  83                

    D)  87

    Correct Answer: A

    Solution :

     \[PC{{l}_{5}}PC{{l}_{3}}+C{{l}_{2}}\] Normal molecular weight of\[PC{{l}_{5}}\] \[=2\times \] vapour density \[=2\times 60=120\] Observed molecular weight of \[PC{{l}_{5}}=30+5\times 35.5\] \[=207.5\] \[i=\frac{Observed\text{ }molecular\text{ }weight}{Normal\text{ }molecular\text{ }weight}=\frac{207.5}{120}=1.73\] Degree of dissociation \[=\frac{i-1}{n-1}=\frac{1.73-1}{2-1}=0.73\] % dissociation\[=0.73\times 100=73%.\]


You need to login to perform this action.
You will be redirected in 3 sec spinner