RAJASTHAN ­ PET Rajasthan PET Solved Paper-2005

  • question_answer
    Which of the following gives iodoform test and Fehling test?

    A)  \[HCHO\]       

    B)  \[C{{H}_{3}}COC{{H}_{3}}\]

    C)  \[C{{H}_{3}}CHO\]       

    D)  \[C{{H}_{3}}C{{H}_{2}}OH\]

    Correct Answer: C

    Solution :

     Acetaldehyde give both iodoform and Fehling test. \[C{{H}_{3}}CHO+{{I}_{2}}+4NaOH\xrightarrow[test]{Iodoform}\] \[\underset{yellow\text{ }ppt}{\mathop{CH{{I}_{3}}}}\,+HCOONa+3{{H}_{2}}O+3NaI\] \[C{{H}_{3}}CHO+\underset{blue}{\mathop{2CuO}}\,\xrightarrow[Fehiling\,test]{\Delta }\] \[C{{H}_{3}}COOH+\underset{red\text{ }ppt}{\mathop{C{{u}_{2}}O}}\,\]


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