Uttarakhand PMT Uttarakhand PMT Solved Paper-2007

  • question_answer
    The Nemst equation giving dependence of electrode potential on concentration is

    A)  \[E=E{}^\circ +\frac{2.303RT}{nF}\log \frac{[M]}{[{{M}^{n+}}]}\]

    B)  \[E=E{}^\circ +\frac{2.303RT}{nF}\log \frac{[{{M}^{n+}}]}{[M]}\]

    C)  \[E=E{}^\circ -\frac{2.303F}{nRT}\log \frac{[{{M}^{n+}}]}{[M]}\]

    D)  \[E=E{}^\circ -\frac{2.303RT}{nF}\log [{{M}^{n+}}]\]

    Correct Answer: B

    Solution :

     For \[{{M}^{n+}}+n{{e}^{-}}\xrightarrow[{}]{{}}M,\] \[E=E{}^\circ -\frac{2.303RT}{nF}\log \frac{M}{[{{M}^{n+}}]}\] \[=E{}^\circ +\frac{2.303RT}{nF}\log \frac{[{{M}^{n+}}]}{[M]}\]


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