VIT Engineering VIT Engineering Solved Paper-2010

  • question_answer
    \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\]and \[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\] exhibit which type of isomerism?

    A)  Geometrical    

    B)  Optical

    C)  Linkage        

    D)  lonisation

    Correct Answer: D

    Solution :

    \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\] and \[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\]give different ions on ionisation as \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\xrightarrow{{}}{{[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]}^{+}}\]                      \[+NO_{2}^{-}\] \[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\xrightarrow{{}}{{[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]}^{+}}\]                     \[+C{{l}^{-}}\] Thus, they show ionisation isomerism.


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