VMMC VMMC Medical Solved Paper-2004

  • question_answer
    When sand is heated with hydrofluoric acid and a wet rod is brought in contact with vapours evolving, a white deposit is due to

    A)  \[Si{{F}_{4}}\]

    B)                                        \[Si{{F}_{2}}\]

    C)  \[{{H}_{4}}Si{{O}_{4}}\]               

    D)         none of these

    Correct Answer: C

    Solution :

    Sand, on heating with HF, give silicon terafluoride vapours, which form silicic acid \[\text{(}{{\text{H}}_{4}}\text{Si}{{\text{O}}_{4}}\text{),}\] on coming in contact with water. \[Si{{O}_{2}}+4HF\xrightarrow{{}}Si{{F}_{4}}+2{{H}_{2}}O\] \[3\,Si{{F}_{4}}+4{{H}_{2}}O\xrightarrow{{}}2{{H}_{2}}Si{{F}_{6}}+\underset{\text{while}}{\mathop{{{H}_{4}}Si{{O}_{4}}}}\,\]


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