VMMC VMMC Medical Solved Paper-2014

  • question_answer
    The activation energy of reaction is zero. 280 K rate constant is\[1.6\times {{10}^{-6}}{{s}^{-1}}.\] The rate constant at 300 K is

    A) zero      

    B) \[3.2\times {{10}^{-6}}{{s}^{-1}}\]

    C) \[1.6\times {{10}^{-5}}{{s}^{-1}}\]                           

    D) \[1.6\times {{10}^{-6}}{{s}^{-1}}\]

    Correct Answer: D

    Solution :

    \[{{E}_{a}}=\frac{2.303R{{T}_{1}}{{T}_{2}}}{({{T}_{2}}-{{T}_{1}})}\log \frac{{{k}_{2}}}{{{k}_{1}}}\] If \[{{E}_{a}}=0,\]then log\[\frac{{{k}_{2}}}{{{k}_{1}}}=0\] \[\therefore \]\[{{k}_{2}}/{{k}_{1}}=1\]or\[{{k}_{1}}={{k}_{2}}\]


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