VMMC VMMC Medical Solved Paper-2014

  • question_answer
    The value of \[{{K}_{p}}\] for the reaction,\[2{{H}_{2}}S(g)2{{H}_{2}}(g)+{{S}_{2}}(g)\]is \[1.2\times {{10}^{-2}}\]\[{{1065}^{o}}C.\] The value for \[{{K}_{c}}\] is

    A) \[<1.2\times {{10}^{-2}}\]                           

    B) \[>1.2\times {{10}^{-2}}\]

    C) \[1.2\times {{10}^{-2}}\]                              

    D) \[0.12\times {{10}^{-2}}\]

    Correct Answer: A

    Solution :

    \[\Delta {{n}_{g}}=\] moles of gaseous products - moles of gaseous reactants,  = 3 ? 2 ? 1 = 0                \[{{K}_{p}}={{K}_{c}}{{(RT)}^{\Delta {{n}_{g}}}}\] \[{{K}_{c}}=\frac{{{K}_{p}}}{RT}\] \[=\frac{1.2\times {{10}^{-2}}}{0.0821\times 1338}\] \[=1.09\times {{10}^{-4}}<1.2\times {{10}^{-2}}\]


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