VMMC VMMC Medical Solved Paper-2015

  • question_answer
    The soldiers of Napolean army while at Alps during freezing winter suffered a serious problem as regards to the tin buttons of their uniforms. White metallic tin buttons got converted   to   grey   powder.   This transformation is related to

    A) a change in the crystalline structure of tin

    B) an interaction with nitrogen of the air at very low temperature

    C) a change in the partial pressure of oxygen in the air

    D) an interaction with water vapour contained in the humid air

    Correct Answer: A

    Solution :

    Tin exists in three solid forms, grey tin, white tin and rhombic tin and all these three forms are inter convertible as \[\text{Grey}\text{White}\text{Rhombic}\] White tin is most stable form. The conversion of white tin in to grey tin takes place very slowly at 18°C. However, the temperature is low -50°C and a small amount of grey. tin is also present. The conversion becomes very rapid. This conversion is known as tin disease or tin post.


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