WB JEE Medical WB JEE Medical Solved Paper-2007

  • question_answer
    In Downs method for the extraction of sodium, the melting point of the electrolyte is lowered by adding

    A)  potassium chloride

    B)  calcium chlpnde

    C)  both calcium chloride and potassium fluoride

    D)  potassium fluoride only

    Correct Answer: C

    Solution :

                     In Down process, sodium is manufactured by the electrolysis of fused sodium chloride in the presence of \[CaC{{l}_{2}}\] and KF using graphite anode and iron cathode \[NaClN{{a}^{+}}+C{{l}^{-}}\]                 \[N{{a}^{+}}{{e}^{-}}\to Na\](at cathode)                 \[2C{{l}^{-}}\to C{{l}_{2}}+2{{e}^{-}}\](at anode) \[CaC{{l}_{2}}+KF\] lower the melting point from the 1085 K to 850 K.


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