WB JEE Medical WB JEE Medical Solved Paper-2007

  • question_answer
    At\[\text{30}{{\,}^{\text{o}}}\text{C}\]  the solubility of \[A{{g}_{2}}C{{O}_{3}}({{K}_{sp}}=8\times {{10}^{-12}})\] would be greatest in one litre of

    A)  \[0.05M\,N{{a}_{2}}C{{O}_{3}}\]              

    B)  \[0.05\,M\,AgN{{O}_{3}}\]

    C)  pure water                       

    D)  \[0.05\,N\,N{{H}_{3}}\]

    Correct Answer: D

    Solution :

                     \[A{{g}_{2}}C{{O}_{3}}2\,A{{g}^{+}}CO_{3}^{2-}\]Due to the common ion effect, the solubility decreases, so the solubility of \[A{{g}_{2}}C{{O}_{3}}\]would be greatest in 1 L of \[\text{0}\text{.05 M N}{{\text{H}}_{\text{3}}}\]due to the absence of common ion either \[A{{g}^{+}}\]or\[CO_{3}^{2-}+A{{g}^{+}}\] form complex with \[\text{N}{{\text{H}}_{\text{3}}}\]\[A{{g}^{+}}+2N{{H}_{3}}\rightleftharpoons {{[Ag{{(N{{H}_{3}})}_{2}}]}^{+}}\]


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