WB JEE Medical WB JEE Medical Solved Paper-2010

  • question_answer
    The potential of a hydrogen electrode at pH=10 is

    A)  0.59 V                                  

    B)  0.00 V

    C)  -0.59 V                                

    D)  -0.059

    Correct Answer: C

    Solution :

                     \[{{H}^{+}}(pH=10)|{{H}_{2}}(1\,atm)|Pt(s)\] Reaction: \[2{{H}^{+}}(pH=10)+2{{e}^{-}}\xrightarrow{{}}{{H}_{2}}(1\,atm)\] \[E={{E}^{o}}-\frac{0.0591}{2}\log \left( \frac{{{p}_{{{H}_{2}}}}}{{{[{{H}^{+}}]}^{2}}} \right)\] \[=0-\frac{0.0591}{2}\log \frac{1}{{{({{10}^{-10}})}^{2}}}\]                 \[=-\frac{0.0591}{2}\times 2\log \frac{1}{{{10}^{-10}}}\] \[=-0.0591\times 10=-0.591\] ie,           \[E=-0.591\,V\]


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