WB JEE Medical WB JEE Medical Solved Paper-2010

  • question_answer
    In the reaction of sodium thiosulphate with \[{{I}_{2}}\]in aqueous medium, the equivalent weight of sodium thiosulphate is equal to

    A)  molar mass of sodium thiosulphate

    B)  the average of molar masses of \[\text{N}{{\text{a}}_{\text{2}}}{{\text{S}}_{\text{2}}}{{\text{O}}_{\text{3}}}\] and 12

    C)  half the molar mass of sodium thiosulphate

    D)  molar mass of sodium thiosulphate \[\times \,\text{2}\]

    Correct Answer: A

    Solution :

                     \[2N{{a}_{2}}{{\overset{+2}{\mathop{S}}\,}_{2}}{{O}_{3}}+{{I}_{2}}\xrightarrow{{}}N{{a}_{2}}\overset{+2.5}{\mathop{{{S}_{4}}}}\,{{O}_{6}}+2NaI\] \[n-\]factor \[=1\] \[E=\frac{M}{1}=M\]


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