WB JEE Medical WB JEE Medical Solved Paper-2012

  • question_answer
    The stable bivalency of Pb and trivalency of Bi is

    A)  due to d contraction in Pb and Bi

    B)  due to relativistic contraction of the 6s orbitals of Pb and Bi, leading to inert pair effect

    C)  due to screening effect

    D)  due to attainment of noble liquid configuration

    Correct Answer: B

    Solution :

     \[_{82}Pb=...6{{s}^{2}}6{{p}^{2}}\] \[_{83}Bi=...6{{s}^{2}}6{{p}^{3}}\] Due to inertness of \[6{{s}^{2}}\] electrons in Pb and Bi, they show bivalency and trivalency respectively instead of tetra and pentavalency.


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