Answer:
Bonding in metal
carbonyls.
The formation of bonds between the metal and carbon atom carbon monoxide is as
described below:
Sigma-overlap involving donation
of lone-pairof electrons on carbon of CO into vacant d-orbital on the metal to
form 
bond.
(ii) Pi-overlap involving donation
of electrons from a filled metal d-orbital of metal into a vacant anti-bonding 
orbital
of CO forming
M
CO
-bond.
Thus, M to C bond
in metal carbonyls consists of a weak C M
sigma bond and M C pi
bond which results due to back-bonding. The back bonding between metal and
carbon atom creates a synergic effect which stabilises the M to C bond,
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