12th Class Chemistry Coordination Chemistry

  • question_answer 45)
        When 0.1 mol  is treated with excess of , 0.2 mol of  are obtained. The conductivity of solution will correspond to (a) 1 : 3 electrolyte                 (b) 1 : 2 electrolyte (c) 1 : 1 electrolyte                 (d) 3 : 1 electrolyte

    Answer:

                        (b) One mole of  precipitates one mole of chloride ion. In the above reaction, when mole  is treated with excess of, 0.2 mole of  are obtained thus, there must be two free chloride ions in the solution of electrolyte. So, molecular formula of complex will be  and electrolytic solution must contain  and two  as constituent ions. Thus, it is 1: 2 electrolyte. Hence, option (b) is the correct.


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