11th Class Chemistry Organic Chemistry: Some Basic Principles & Techniques / कार्बनिक रसायन : कुछ मूलभूत सिद्धांत एवं तकन

  • question_answer 31)
     Predict the conditions under which aluminium might be expected to reduce magnesium oxide.

    Answer:

    The equations for the formation of the two oxides are: 4/3AI(s) + O2(g) 2/3AI2O3(s) 2Mg(s) + O2(g) 2MgO(s) If we look at the plots for the formation of the two oxides on the Ellingham diagram, we find that the value of Al2O3, at temperatures below 1623 K, is less negative than that of MgO. Thus, of the reaction 2Mg + 2/3Al2O3 2MgO + 4/3 Al is negative. Therefore, below 1623 K, Mg can reduce Al2O3 to Al. However above 1623 K, the   value for Al2O3 is more negative than that of MgO. Thus, of the reaction; 4/3 Al + 2 MgO 2/3Al2O3 + 2Mg is negative. Therefore above 1623 K, Al can reduce MgO to Mg.  


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