12th Class Chemistry Haloalkanes and Haloarenes / हैलोएल्केन तथा हैलोएरीन्स

  • question_answer 24)
    Write the mechanism of the following reaction.    

    Answer:

    (i) Write the resonating structures of KCN.   Resonating forms of KCN are the following.     Cyanide ion is an ambident nucleophile. It can attack through C-atom or through N-atom. Thus, two possible products are cyanides and isocyanides respectively. Here in the presence of the polar solvent, KCNreadily ionises to furnish ions. As C?C bond is more stable than C?Nbond, so cyanide is predominantly formed.      


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