12th Class Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व

  • question_answer 21)
      Explain giving reasons : (a) Transition metals and many of their compounds show paramagnetic behaviour. (b) Transition metals have high enthalpy of atomisation. (c) The transition metals generally form coloured compounds. (d) Transitional metals and their many compounds act as good catalysts.

    Answer:

    (a) Transition metals or their ions are usually paramagnetic (attracted by the magnet) due to the presence of unpaired electrons. More is the number of unpaired electrons, more is the paramagnetic character and more is magnetic moment. Magnetic moment in case of Transition metals arise due to the spin motion of e?. Magnetic moment is calculated by spin only formula  where = magnetic moment, n = no. of unpaired electrons. e.g., Fe (III) : [Ar] 3d5 Ithasfive unpaired electron: (b) In transition elements there operate two types of forces i.e. (i)Metallic bond forces and (ii) Strong covalent bond forces between the atoms due to greater number of unpaired electrons and mutual d-d overlapping. Both these forces will have to be broken in order to atomize transition elements. For this, a lot heat is required. Hence transition metals have high enthalpy of atomization. (c) Transition metals, ions or their aqueous solutions are usually coloured. This is due to the presence of partially filled d-subshell (or presence of unpaired electrons). So, unpaired electron undergo transition within the d-subshell (d?d transition) for which small amount of energy is required from the visible region. Thus, one colour is absorbed and the complementary colour is emitted e.g. CuSO4.5H2O has one unpaired electron, it adsorbs orange colour from visible region and complementary blue colour is emitted. Hence, it looks blue in colour. (d) (i) Transition metals have vacant d-orbitals, so it accepts the tone pair of reactants to form unstable intermediate compound. Therefore, it provides surface for the adsorption of reactant and also activate them so that the reaction becomes fast and then unstable intermedia: compound decomposes to give the product and catalyst is regenerated. (ii) Transition metal act as catalyst because they provide a low energy path for the reaction to take place by the change their oxidation state. e.g. The net reaction is


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