12th Class Chemistry The p-block Elements-II / p-ब्लॉक तत्व-II

  • question_answer 4)
    Mention the conditions to maximise the yield of ammonia.

    Answer:

    Ammonia is prepared on commercial scale by Haber's Process from dinitrogen and dihydrogen by the following chemical reaction N2 (g) + 3H2(g)  2NH3(g) ;H = ?46.1 kJ mol?1 The favourable conditions for the forward reactions are derived from Le-Chatelier's principle. These are: (a) Low temperature. Low temperature should favour the formation of ammonia as the forward reaction is exothermic. But an optimum temperature of nearly 700 K is necessary to keep the reaction in progress. (b) High Pressure. High pressure (about 200 atm or 200 x 105 Pa) is needed to favour the formation of ammonia because number of moles (gaseous) decrease in the forward reaction. (c) Catalyst. The rate of reaction can be accelerated by using finely divided iron oxide as catalyst with traces of K2O or Al2O3 or molybdenum acting as a promoter for the catalyst.  


You need to login to perform this action.
You will be redirected in 3 sec spinner