Answer:
(i) \[\underset{\text{2,}\,\text{3-Dimethylbutan-2-ol}}{\mathop{\overset{1}{\mathop{C{{H}_{3}}}}\,-\underset{\begin{smallmatrix}
| \\
OH
\end{smallmatrix}}{\overset{\begin{smallmatrix}
\,\,C{{H}_{3}} \\
|
\end{smallmatrix}}{\mathop{2CH}}}\,-\overset{3}{\mathop{C}}\,H-\overset{4}{\mathop{C}}\,{{H}_{3}}}}\,\]
(ii)\[\underset{\begin{smallmatrix}
\\
\text{4-Methylpentan-2-ol}
\end{smallmatrix}}{\mathop{\overset{5}{\mathop{C}}\,{{H}_{3}}-\overset{\begin{smallmatrix}
C{{H}_{3}} \\
4|
\end{smallmatrix}}{\mathop{C}}\,H-\overset{3}{\mathop{C}}\,{{H}_{2}}-\underset{\begin{smallmatrix}
| \\
OH
\end{smallmatrix}}{\mathop{\overset{2}{\mathop{C}}\,}}\,H-\overset{1}{\mathop{C}}\,{{H}_{3}}}}\,\]
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