Answer:
Four structural isomers are possible. These are:
\[\underset{\text{1,}\,\text{1-Dichloropropane}}{\mathop{\overset{3}{\mathop{C}}\,{{H}_{3}}-\overset{2}{\mathop{C}}\,{{H}_{2}}-\underset{\begin{smallmatrix} | \\ Cl \end{smallmatrix}}{\mathop{\overset{1}{\mathop{C}}\,H}}\,-Cl}}\,\] \[\underset{\text{1,}\,2\text{-Dichloropropane}}{\mathop{\overset{3}{\mathop{C}}\,{{H}_{3}}-\underset{\begin{smallmatrix} | \\ Cl \end{smallmatrix}}{\mathop{\overset{2}{\mathop{C}}\,H}}\,-\underset{\begin{smallmatrix} | \\ Cl \end{smallmatrix}}{\mathop{\overset{1}{\mathop{C}}\,{{H}_{2}}}}\,}}\,\] \[\underset{\text{2,}\,\text{2-Dichloropropane}}{\mathop{\overset{3}{\mathop{C}}\,{{H}_{3}}-\underset{\begin{smallmatrix} | \\ Cl \end{smallmatrix}}{\overset{\begin{smallmatrix} Cl \\ | \end{smallmatrix}}{\mathop{{{C}^{2}}}}}\,-\overset{1}{\mathop{C}}\,{{H}_{3}}}}\,\] \[\underset{\text{1,}\,\,\text{3-Dichloropropane}}{\mathop{Cl-\overset{3}{\mathop{C}}\,{{H}_{2}}-\overset{2}{\mathop{C}}\,{{H}_{2}}-\overset{1}{\mathop{C}}\,{{H}_{2}}-Cl}}\,\]
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