A) I and II
B) I and IV
C) II and III
D) I and III
Correct Answer: B
Solution :
Due to strong negative inductive effect shown by ?Cl and \[-OCOC{{H}_{3}}\]group, acid chloride and acid anhydride are highly reactive among acid derivatives. They react independently with water even in the absence of catalyst to give carboxylic acid. \[C{{H}_{3}}-\overset{O}{\mathop{\overset{|\,\,|}{\mathop{C}}\,}}\,-Cl\xrightarrow{NaHC{{O}_{3}}(aq)}C{{H}_{3}}-\overset{O}{\mathop{\overset{|\,\,|}{\mathop{C}}\,}}\,-ONa\] \[+C{{O}_{2}}+HCl\] \[C{{H}_{3}}\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-O-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,C{{H}_{3}}\xrightarrow{NaHC{{O}_{3}}(aq)}\]\[2C{{H}_{3}}-\overset{O}{\mathop{\overset{|\,\,|}{\mathop{C}}\,}}\,-ONa+C{{O}_{2}}\]You need to login to perform this action.
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