12th Class Chemistry Aldehydes, Ketones and Carboxylic Acids / ऐल्डिहाइड, कीटोन तथा कर्बोक्सिलिक अम्ल

  • question_answer 19)
    An organic compound (A) (molecular formula was hydrolysed with dilute sulphuric acid to give a carhoxylic acid (B)and alcohol (C). Oxidation of (C) with chromic acid produced (B). (C)on dehydration gives but-1-ene. Write equations for the reactionsinvolved. (i) Ester produces a carboxylic acid and an alcohol on hydrolysis. (ii) Ester (A) has 8 C-atoms, calculate the number of carbon atoms in acid and alcohol. (iii) Guess the alcohol and the acid according to the given reactions. (iv) Now guess the ester (v) Write all the related equations,  

    Answer:

    (i) Since, [A] produces carboxylic acid [B] and an alcohol [C]on hydrolylsis, compound [A] is an ester. (ii) Alcohol [C] on oxidation produces acid [B]. It means both [B] and[C] have same number of carbon atoms, i.e., four each. (v) The equations for all the above reactions: are:    


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