# Solved papers for JCECE Medical JCECE Medical Solved Paper-2008

### done JCECE Medical Solved Paper-2008

• question_answer1) A particle moves in a straight line with retardation proportional to its displacement. Its loss of kinetic energy for any displacement $x$ is proportional to

A) ${{x}^{2}}$

B) ${{e}^{x}}$

C) $x$

D) ${{\log }_{e}}x$

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• question_answer2) A ball is thrown from a point with a speed ${{\text{v}}_{\text{0}}}$at an angle of projection $\theta .$From the same point and at the same instant, a person starts running with a constant speed $\frac{{{v}_{0}}}{2}$to catch the ball. Will the person be able to catch the ball? If yes, what should be the angle of projection?

A) Yes,${{60}^{o}}$

B) Yes, ${{30}^{o}}$

C) No

D) Yes, ${{45}^{o}}$

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• question_answer3) Spherical balls of radius R are falling in a viscous fluid of viscosity $\eta$with a velocity v. The retarding viscous force acting on the spherical ball is

A)  directly proportional to R but inversely proportional to v

B)  directly proportional to both radius R and velocity v

C)  inversely proportional to both radius R and velocity v

D)  inversely proportional to R but directly proportional to velocity $v$

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• question_answer4) Nickel shows ferromagnetic property at room temperature. If the temperature is increased beyond Curie temperature, then it will show

A) paramagnetism

B) anti-ferromagnetism

C) no magnetic property,

D) diamagnetism

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• question_answer5) In radioactive decay process, the negatively charged emitted (3-particles are

A) the electrons present inside the nucleus

B) the electrons produced as a result of the decay of neutrons inside the nucleus

C) the electrons produced as a result of collisions between atoms

D) the electrons orbiting around the nucleus

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• question_answer6) What is the value of inductance L for which the current is a maximum in a series LCR circuit with $C=10\mu F$and$\omega =1000\,{{s}^{-1}}$?

A) $100\,mH$

B) $1\,mH$

C) Cannot be calculated unless R is known

D) $10\text{ }mH$

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• question_answer7) Three point charges $+\,q,-2q$and $+q$are placed at points $(x=0,y=a,z=0),$$(x=0,y=0,z=0)$and$(x=a,y=0,z=0),$ respectively. The magnitude and direction of the electric dipole moment vector of this charge assembly are

A) $\sqrt{2}\,qa$along $+y$direction

B) $\sqrt{2}qa$ along the line joining points $(x=0,y=0,z=0)$and $(x=a,y=a,z=0)$

C) $qa$along the line joining points $(x=0,y=0,z=0)$ and $(x=a,y=a,z=0)$

D) $\sqrt{2}qa$along $+x$direction

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• question_answer8) The following figure shows a logic gate circuit with two inputs A and B and the output C. The voltage waveforms of A, B and C are as shown below The logic circuit gate is

A) AND gate

B) NAND gate

C) NOR gate

D) OR gate

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• question_answer9) Assuming the sun to have a spherical outer surface of radius r, radiating like a black body at temperature $t{{\,}^{o}}C,$the power received by a unit surface, (normal to the incident rays) at a distance R from the centre of the sun is

A) $\frac{4\pi {{r}^{2}}\sigma {{t}^{4}}}{{{R}^{2}}}$

B)  $\frac{{{r}^{2}}\sigma {{(t+273)}^{4}}}{4\pi {{R}^{2}}}$

C)  $\frac{16{{\pi }^{2}}{{r}^{2}}\sigma {{t}^{4}}}{{{R}^{2}}}$

D)  $\frac{{{r}^{2}}\sigma {{(t\,+273)}^{4}}}{{{R}^{2}}}$

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• question_answer10) The temperature of the two outer surfaces of a composite slab, consisting of two materials having coefficients of thermal conductivity K and 2K and thickness $x$and $4x,$ respectively are ${{T}_{2}}$and ${{T}_{1}}({{T}_{2}}>{{T}_{1}}).$ The rate of heat transfer through the slab, in a steady state is$\left( \frac{A({{T}_{2-}}{{T}_{1}})K}{x} \right)f,$ with $f$ equals to A) 1

B) 1/2

C) 2/3

D) 1/3

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• question_answer11) The maximum number of possible interference maxima for slit-separation equal 'to twice the wavelength in Young?s double-slit experiment, is

A) infinite

B) five

C) three

D) zero

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• question_answer12) Two spherical conductors B and C having equal radii and carrying equal charges in them repel each other with a 'force F when kept apart at some distance. A third spherical conductor having same radius as that of B but uncharged, is brought in contact with B, then brought in contact with C and finally removed away from both. The new force of repulsion between B>> and C is

A) $\frac{F}{4}$

B) $\frac{3F}{4}$

C) $\frac{F}{8}$

D) $\frac{3F}{8}$

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• question_answer13) In gamma ray emission from a nucleus

A) both the neutron number and the proton number change

B) there is no change in the proton number and the neutron number

C) only the neutron number changes

D) only the proton number changes

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• question_answer14) A particle starting from the origin (0, 0) moves in a straight line in the $(x,y)$ plane. Its coordinates at a later time are $(\sqrt{3},3).$ The path of the particle makes with the $x-$axis an angle of

A) ${{30}^{0}}$

B) ${{45}^{o}}$

C) ${{60}^{o}}$

D) ${{0}^{o}}$

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• question_answer15) The resistance of an ammeter is $13\,\Omega$ and its scale is graduated for a current upto 100 A. After an .additional shunt has been connected to this ammeter it becomes possible to measure currents upto 750 A by this meter. The value of shunt resistance is

A) $20\,\Omega$

B) $2\,\Omega$

C) $0.2\,\,\Omega$

D) $2\,k\Omega$

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• question_answer16) The primary and secondary coils of a transformer have 50 and 1500 turns respectively. If the magnetic flux $\text{o }\!\!|\!\!\text{ }$ linked with the primary coil is given by$\text{o }\!\!|\!\!\text{ =}\,\text{o}{{\text{ }\!\!|\!\!\text{ }}_{0}}+4t,$ where $\text{o }\!\!|\!\!\text{ }$is in weber, t is time in second and $\,\text{o}{{\text{ }\!\!|\!\!\text{ }}_{0}}$ is a constant, the output voltage across the secondary coil is

A) 90 V

B) 120 V

C) 220 V

D) 30 V

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• question_answer17) A uniform rod AB of length I and mass m is free to rotate about point A. The rod is released from rest in the horizontal position. Given that the moment of inertia of the rod about A is $\frac{m{{l}^{2}}}{3},$ the initial angular acceleration of the rod will be A) $\frac{2g}{3l}$

B) $mg\frac{l}{2}$

C) $\frac{3}{2}gl$

D) $\frac{3g}{2l}$

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• question_answer18) In the energy band diagram of a material shown below, the open circles and filled circles denote holes and electrons respectively. The material is a/an A) p-type semiconductor

B) insulator

C) metal

D) $n-$type semiconductor

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• question_answer19) A particle executes simple harmonic oscillation with an amplitude a. The period of oscillation is T. The minimum time taken by the particle to travel half of the amplitude from the equilibrium position is

A) $\frac{T}{4}$

B) $\frac{T}{8}$

C) $\frac{T}{12}$

D) $\frac{T}{2}$

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• question_answer20) A block B is pushed momentarily along a horizontal surface with an initial velocity $v.$If $\mu$is the coefficient of sliding friction between B and the surface, block B will come to rest after a time A) $\frac{v}{g\mu }$

B) $\frac{g\mu }{v}$

C) $\frac{g}{v}$

D) $\frac{v}{g}$

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• question_answer21) A transformer is used to light a 100 W and 110 V lamp from a 220 V mains. If the main current is 0.5 A, the efficiency of the transformer is approximately

A) 30%

B) 50%

C) 90%

D) 10%

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• question_answer22) A Steady current of 1.5 A flows through a copper voltameter for 10 min. If the electrochemical equivalent of copper is $30\times {{10}^{-5}}g\,{{C}^{-1}},$ the mass of copper deposited on the electrode will be

A) 0.40 g

B) 0.50 g

C) 0.67 g

D) 0.27 g

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• question_answer23) Three resistances P, Q, R each of $2\Omega$and an unknown resistance S form the four arms of a Wheatstone's bridge circuit. When a resistance of $6\,\Omega$ is connected in parallel to S the bridge gets balanced. What is the value of S?

A) $2\,\Omega$

B) $3\,\Omega$

C) $6\,\Omega$

D) $1\,\Omega$

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• question_answer24) A mass of 2.0 kg is put on a flat pan attached to a vertical spring fixed on the ground as shown in the figure. The mass of the spring and the pan is negligible. When pressed slightly and released the mass executes a simple harmonic motion. The spring constant is 200 N/m. What should be the minimum amplitude of the motion, so that the mass gets detached from the pan? (Take$g=10\,m/{{s}^{2}}$)

A) 8.0 cm

B) 10.0cm

C) Any value less than 12.0 cm

D) 4.0 cm

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• question_answer25) Two satellites of earth, ${{\text{S}}_{\text{1}}}$and ${{\text{S}}_{2}}$are moving in the same orbit. The mass of ${{\text{S}}_{1}}$is four times the mass of ${{\text{S}}_{2}}.$Which one of the following statements is true?

A) The time period of ${{\text{S}}_{1}}$is four times that of ${{\text{S}}_{2}}.$

B) The potential energies of earth and satellite in the two cases are equal

C) ${{\text{S}}_{1}}$and ${{\text{S}}_{2}}$are moving with the same speed.

D) The kinetic energies of the two satellites are equal.

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• question_answer26) Charges $+q$and$~-q$ are placed at points A and B respectively which are a distance 2 L apart, C is the midpoint between A and B. The work done in moving a charge $+Q$along the semicircle CRD is A) $\frac{qQ}{4\pi {{\varepsilon }_{0}}L}$

B) $\frac{qQ}{2\pi {{\varepsilon }_{0}}L}$

C) $\frac{qQ}{6\pi {{\varepsilon }_{0}}L}$

D) $-\frac{qQ}{6\pi {{\varepsilon }_{0}}L}$

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• question_answer27) A beam of electrons passes undeflected through mutually perpendicular electric and magnetic fields. If the electric field is switched off, and the same magnetic field is maintained, the electrons move

A) in an elliptical orbit

B) in a circular orbit

C) along a parabolic path

D) along a straight line

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• question_answer28) Monochromatic light of frequency $\text{6}\text{.0}\,\text{ }\!\!\times\!\!\text{ }\,\,\text{1}{{\text{0}}^{\text{14}}}\text{ Hz}$is produced by a laser. The power emitted is $2\times {{10}^{-3}}W.$The number of photons emitted, on the average, by the source per second is

A) $5\times {{10}^{15}}$

B) $5\times {{10}^{16}}$

C) $5\times {{10}^{17}}$

D) $5\times {{10}^{14}}$

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• question_answer29) The diagram shows the energy levels for an electron in a certain atom. Which transition shown represents the emission of a photon with the most energy? A) III

B) IV

C) I

D) II

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• question_answer30) In the circuit, the galvanometer G shows zero deflection. If the batteries A and B have negligible internal resistance, the value of the resistor R will be A) $200\,\Omega$

B) $100\,\Omega$

C) $500\,\Omega$

D) $1000\,\Omega$

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• question_answer31) When an unpolarized light of intensity ${{\text{I}}_{\text{0}}}$is incident on a polarizing sheet, the intensity of the light which does not get transmitted is

A) $\frac{1}{2}{{I}_{0}}$

B) $\frac{1}{4}{{I}_{0}}$

C) zero

D) ${{I}_{0}}$

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• question_answer32) An observer moves towards a stationary source of sound, with a velocity one-fifth of the velocity of sound. What is the percentage increase in the apparent frequency?

A) Zero

B) 0.5%

C) 5%

D) 20%

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• question_answer33) A particle of mass 100 g is thrown vertically upwards with a speed of 5 m/s. The work done by the force of gravity during the time the particle goes up is

A) $-0.5\,J$

B) $-1.25\,J$

C) $1.25\,J$

D) $0.5\,J$

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• question_answer34) A mass of M kg is suspended by a weightless string. The horizontal force that is required to displace it until the string makes an angle of ${{45}^{o}}$ with the initial vertical direction is

A) $Mg(\sqrt{2}+1)$

B) $Mg\sqrt{2}$

C) $\frac{Mg}{\sqrt{2}}$

D) $Mg(\sqrt{2}-1)$

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• question_answer35) An electric charge ${{10}^{-3}}\,\mu C$is placed at the origin (0, 0) of X-Y coordinate system. Two points A and B are situated at $(\sqrt{2},\sqrt{2})$ and (2, 0) respectively. The potential difference between the points A and B will be

A) 9 V

B) zero

C) 2 V

D) 4.5 V

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• question_answer36) A circular disc of radius R is removed from a bigger circular disc of radius 2R, such that the circumference of the discs coincide. The centre of mass of the new disc is $\alpha R$from the centre of the bigger disc. The value of $\alpha$is

A) 1/3

B) 1/2

C) 1/6

D) 1/4

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• question_answer37) A common-emitter amplifier has a voltage gain of 50, an input impedance of $100\,\Omega$ and an output impedance of $200\,\Omega .$ The power gain of the amplifier is

A) 500

B) 1000

C) 1250

D) 100

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• question_answer38) A vertical spring with force constant k is fixed on a table. A ball of mass $m$at a height h above the free upper end of the spring falls vertically on the spring, so that the spring is compressed by a distance d. The net work done in the process is

A) $mg(h+d)+\frac{1}{2}k{{d}^{2}}$

B) $mg(h+d)-\frac{1}{2}k{{d}^{2}}$

C) $mg(h-d)-\frac{1}{2}k{{d}^{2}}$

D) $mg(h-d)+\frac{1}{2}k{{d}^{2}}$

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• question_answer39) Dimensions of resistance in an electrical circuit, in terms of dimension of mass M, of length L, of time T and of current I, would be

A) $[M{{L}^{2}}{{T}^{-3}}{{I}^{-1}}]$

B) $[M{{L}^{2}}{{T}^{-2}}]$

C) $[M{{L}^{2}}{{T}^{-1}}{{I}^{-1}}]$

D) $[M{{L}^{2}}{{T}^{-3}}{{I}^{-2}}]$

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• question_answer40) The work of 146 kJ is performed in order to compress one kilo mole of a gas adiabatically and in this process the temperature of the gas increases by ${{\text{7}}^{\text{o}}}\text{C}\text{.}$ The gas is$(R=8.3\,\text{J}\,\text{mo}{{\text{l}}^{-1}}{{K}^{-1}})$

A) diatomic

B) triatomic

C) a mixture of monoatomic and diatomic

D) monoatomic

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• question_answer41) Diwali rocket is ejecting 50 g of gases/sec at a velocity of 400 m/s. The accelerating force on the rocket will be

A) 22 dyne

B) 20 N

C) 20 dyne

D) 100 N

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• question_answer42) A frame made of metallic wire enclosing a surface area A is covered with a soap film. If the area of the frame of metallic wire is reduced by 50%, the energy of the soap film will be changed by

A) 100%

B) 75%

C) 50%

D) 25%

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• question_answer43) A symmetric double convex lens is cut in two equal parts by a plane perpendicular to the principal axis. If the power of the original lens is 4D, the power of a cut lens will be

A) 2D

B) 3D

C) 4D

D) 5D

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• question_answer44) Two non-ideal batteries are connected in parallel. Consider the following statements. (i) The equivalent emf is smaller than either of the two emfs. (ii) The equivalent internal resistance is smaller than either of the two internal resistances.

A) Both (i) and (ii) are correct

B) (i) is correct but (ii) is wrong

C) (ii) is correct but (i) is wrong

D) Both (i) and (ii) are wrong

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• question_answer45) The period of oscillation of a simple pendulum is given by $T=2\pi \sqrt{\frac{l}{g}},$where $l$is about 100 cm V and is known to have 1 mm accuracy. The period is about 2s. The time of 100 oscillations is measured by a stop watch of least count s. The percentage error in g is

A) 0.1%

B) 1%

C) 0.2%

D) 0.8%

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• question_answer46) The mass of the earth is 6.00 x 1024 kg and that of the moon is $7.40\times {{10}^{22}}kg.$ The constant of gravitation $G=6.67\times {{10}^{-11}}\,N-{{m}^{2}}/k{{g}^{2}}.$The potential energy of the system is $-7.79\times {{10}^{23}}\,J.$ The mean distance between the earth and moon is

A) $~3.80\times {{10}^{8}}m$

B) $~3.37\times {{10}^{6}}m$

C) $~7.60\times {{10}^{4}}\text{ }m$

D) $~1.90\times {{10}^{2}}\text{ }m$

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• question_answer47) If a rubber ball is taken at the depth of 200m in a pool, its volume decreases by 0.1%. If the density of water is $\text{1 }\!\!\times\!\!\text{ 1}{{\text{0}}^{\text{3}}}\,\text{kg/}{{\text{m}}^{\text{3}}}$and $g=10\,m/{{s}^{2}},$then the volume of elasticity in $\text{N/}{{\text{m}}^{\text{2}}}$will be

A) $\text{1}{{\text{0}}^{8}}$

B) $\text{2}\times \text{1}{{\text{0}}^{8}}$

C) $\text{1}{{\text{0}}^{9}}$

D) $\text{2}\times \text{1}{{\text{0}}^{9}}$

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• question_answer48) At 100K and 0.1 atmospheric pressure, the volume of helium gas is 10 L. If volume and pressure are doubled its temperature will change to

A) 400 K

B) 127 K

C) 200 K

D) 25 K

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• question_answer49) An organ pipe ${{\text{P}}_{\text{1}}}$closed at one end vibrating in its first overtone and another pipe ${{\text{P}}_{2}}$open at both ends vibrating in its third overtone are in resonance with a given tuning fork. The ratio of lengths of ${{\text{P}}_{\text{1}}}$and${{\text{P}}_{2}}$ is

A) 1:2

B) 1 : 3

C) 3 : 8

D) 3 : 4

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• question_answer50) Fraunhofer spectrum is a

A) line absorption spectrum

B) band absorption spectrum

C) line emission spectrum

D) band emission spectrum

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• question_answer51) How many unit cells are present in a cube shaped ideal crystal of $\text{NaCl}$of mass 1.00 g? [Atomic masses :$\text{Na}\,\text{=}\,\text{23,}\,\text{Cl}\,\text{=}\,\text{35}\text{.5}$

A) $2.57\times {{10}^{21}}$

B) $5.14\times {{10}^{21}}$

C) $1.28\times {{10}^{21}}$

D) $1.71\times {{10}^{21}}$

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• question_answer52) In acidic medium dichromate ion oxidises ferrous ion to ferric ion. If gram molecular weight of potassium dichromate is 294 g, its gram equivalent weight is

A) 294 g

B) 127g

C) 49 g

D) 24.5 g

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• question_answer53) When$C{{H}_{2}}=CH-COOH$ is reduced with $\text{LiAl}{{\text{H}}_{\text{4}}}\text{,}$the compound obtained will be

A) $\text{C}{{\text{H}}_{3}}-C{{H}_{2}}-COOH$

B) $C{{H}_{2}}=CH-C{{H}_{2}}OH$

C) $C{{H}_{3}}-C{{H}_{2}}-C{{H}_{2}}OH$

D) $C{{H}_{3}}-C{{H}_{2}}-CHO$

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• question_answer54) Which one of the following compounds has the smallest bond angle in its molecule?

A) $S{{O}_{2}}$

B) $O{{H}_{2}}$

C) $S{{H}_{2}}$

D) $N{{H}_{3}}$

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• question_answer55) For the redox reaction $Zn(s)+C{{u}^{2+}}(0.1\,M)\xrightarrow{{}}Z{{n}^{2+}}(1.M)+Cu(s)$ taking place in a cell, $\text{E}_{\text{cell}}^{\text{o}}$is$\text{1}\text{.10}\,\text{V}\text{.}{{\text{E}}_{\text{cell}}}$ for the cell will be $\left( 2.303\frac{RT}{F}=0.0591 \right)$

A) 2.14 V

B) 1.80 V

C) 1.07 V

D) 0.82 V

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• question_answer56) The rate law for a reaction between the substances A and B is given by rate $=k{{[A]}^{n}}{{[B]}^{m}}.$ On doubling the concentration of A and halving the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as

A) $\frac{1}{{{2}^{m+n}}}$

B) $(m+n)$

C) $(n-m)$

D) ${{2}^{(n-m)}}$

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• question_answer57) If at 298 K the bond energies of $C-H,C-C,C=C$and $H-H$bonds are respectively 414, 347, 615 and $435\,\text{kJ}\,\text{mo}{{\text{l}}^{-1}},$ the value of enthalpy change for the reaction ${{H}_{2}}C=C{{H}_{2}}(g)+\xrightarrow{{}}{{H}_{3}}C-C{{H}_{3}}(g)$at $298\,K$will be

A) $+250\,kJ$

B) $-250\,kJ$

C) $+125\,kJ$

D) $-125\,kJ$

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• question_answer58) Which one of the following characteristics is not correct for physical adsorption?

A) Adsorption on solids is reversible

B) Adsorption increases with increase in temperature

C) Adsorption is spontaneous

D) Both enthalpy and entropy of adsorption are negative

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• question_answer59) The correct order of increasing basic nature for the bases $\text{N}{{\text{H}}_{\text{3}}}\text{,C}{{\text{H}}_{\text{3}}}\text{N}{{\text{H}}_{\text{2}}}$and ${{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{2}}}\text{NH}$is

A) $C{{H}_{3}}N{{H}_{2}}<N{{H}_{3}}<{{(C{{H}_{3}})}_{2}}NH$

B) ${{(C{{H}_{3}})}_{2}}NH<N{{H}_{3}}<C{{H}_{3}}N{{H}_{2}}$

C) $N{{H}_{3}}<C{{H}_{3}}N{{H}_{2}}<{{(C{{H}_{3}})}_{2}}NH$

D) $C{{H}_{3}}N{{H}_{2}}<{{(C{{H}_{3}})}_{2}}NH<N{{H}_{3}}$

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• question_answer60) Nylon threads are made up of

A) polyvinyl polymer

B) polyester polymer

C) polyamide polymer

D) polyethylene polymer

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• question_answer61) Due to presence of an unpaired electron, free radicals are

A) cations

B) anions

C) chemically inactive

D) chemically reactive

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• question_answer62) The highest electrical conductivity among the following aqueous solutions, is of

A) 0.1 M difluoroacetic acid

B) 0.1 M fluoroacetic acid

C) 0.1 M chloroacetic acid

D) 0.1 M acetic acid

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• question_answer63) Aluminium oxide may be electrolysed at $\text{1000}{{\,}^{\text{o}}}\text{C}$to furnish aluminium metal (atomic mass$=27\,u;\,1F=96,500\,C$). The cathode reaction is Z$A{{l}^{3+}}+3{{e}^{-}}\xrightarrow{{}}A{{l}^{0}}$ To prepare 5.12 kg of aluminium metal by this method would require

A) $5.49\,\,\times \,\,{{10}^{1}}C$ of electricity

B) $5.49\,\,\times \,\,{{10}^{4}}C$of electricity

C) $1.83\times {{10}^{7}}C$of electricity

D) $5.49\times {{10}^{7}}C$of electricity

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• question_answer64) The molecular shapes of $\text{S}{{\text{F}}_{\text{4}}}\text{,}\,\text{Si}{{\text{F}}_{\text{4}}}$and $\text{ICl}_{4}^{-}$are

A) different with 1, 0 and 2 lone pairs of electrons on the central atoms, respectively

B) different with 0, 1 and 2 lone pairs of electrons on the central atoms, respectively

C) the same with 1, 1 and 1 lone pair of electrons on the central atoms, respectively

D) the same with 2, 0 and 1 lone pairs of electrons on the central atoms, respectively

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• question_answer65) Calomel $(H{{g}_{2}}C{{l}_{2}})$ on reaction with ammonium hydroxide gives

A) $HgO$

B) $H{{g}_{2}}O$

C) $N{{H}_{2}}-Hg-Hg-Cl$

D) $HgN{{H}_{2}}Cl$

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• question_answer66) Alkyl halides react with dialkyl copper reagents to give

A) alkenyl halides

B) alkanes

C) alkyl copper halides

D) alkenes

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• question_answer67) Acid catalysed hydration of alkenes except ethene leads to the formation of

A) mixture of secondary and tertiary alcohols

B) mixture of primary and secondary alcohols

C) secondary or tertiary alcohol

D) primary alcohol

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• question_answer68) An aqueous solution of 6.3 g of oxalic acid dihydrate is made upto 250 mL. The volume of $\text{0}\text{.1}\,\text{N}\,\text{NaOH}$required to completely neutralize 10 mL of this solution is

A) $\text{40 mL}$

B) $\text{20 mL}$

C) $10\,mL$

D) $4\,mL$

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• question_answer69) The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to stationary state one, would be (Rydberg constant$=1.097\times {{10}^{7}}\,{{m}^{-1}}$)

A) 91 nm

B) 192 nm

C) 406 nm

D) $9.1\times {{10}^{-8}}\,nm$

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• question_answer70) Which one of the following aqueous solutions will exhibit highest boiling point?

A) $0.01\,M\,N{{a}_{2}}S{{O}_{4}}$

B) $0.01\,M\,KN{{O}_{3}}$

C) $0.015\,M\,\text{urea}$

D) $0.015\,M\,\text{glucose}$

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• question_answer71) Which among the following factors is the most important in making fluorine the strongest oxidising agent?

A) Electron affinity

B) Ionisation enthalpy

C) Hydration enthalpy

D) Bond dissociation energy

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• question_answer72) What is the equilibrium expression for the reaction, ${{P}_{4}}(s)+5{{O}_{2}}(g){{P}_{4}}{{O}_{10}}(s)?$

A) ${{K}_{c}}=\frac{[{{P}_{4}}{{O}_{10}}]}{[{{P}_{4}}]{{[{{O}_{2}}]}^{5}}}$

B) ${{K}_{c}}=\frac{[{{P}_{4}}{{O}_{10}}]}{5[{{P}_{4}}][{{O}_{2}}]}$

C) ${{K}_{c}}={{[{{O}_{2}}]}^{5}}$

D) ${{K}_{c}}=\frac{1}{{{[{{O}_{2}}]}^{5}}}$

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• question_answer73) The enthalpies of combustion of carbon and carbon monoxide are$-393.5$and$-283\,\text{kJ}\,\text{mo}{{\text{l}}^{-1}}$ respectively. The enthalpy of formation of carbon monoxide per mol is

A) $110.5\,kJ$

B) $676.5\,kJ$

C) $-676.5\,kJ$

D) $-110.5\,kJ$

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• question_answer74) Which one of the following ores is best concentrated by froth-floatation method?

A) Magnetite

B) Cassiterite

C) Galena

D) Malachite

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• question_answer75) Excess of KI reacts with $\text{CuS}{{\text{O}}_{\text{4}}}$solution and then $\text{N}{{\text{a}}_{\text{2}}}{{\text{S}}_{\text{2}}}{{\text{O}}_{\text{3}}}$solution is added to it. Which of the statements is incorrect for this reaction?

A) $\text{C}{{\text{u}}_{\text{2}}}{{\text{I}}_{\text{2}}}$ is formed

B) $\text{Cu}{{\text{I}}_{2}}$ is formed

C) $\text{N}{{\text{a}}_{\text{2}}}{{\text{S}}_{\text{2}}}{{\text{O}}_{\text{3}}}$is oxidised

D) Evolved ${{\text{I}}_{2}}$ is reduced

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• question_answer76) Which one of the following does not have sp2 hybridised carbon?

A) Acetone

B) Acetic acid

C) Acetonitrile

D) Acetamide

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• question_answer77) Which of the following will have a meso-isomer also?

A) 2-chlorobutane

B) 2, 3-dichlorobutane

C) 2, 3-dichloropentane

D) 2-hydroxypropanoic acid

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• question_answer78) Consider the acidity of the carboxylic adds (i) $PhCOOH$ (ii) $o-N{{O}_{2}}{{C}_{6}}{{H}_{4}}COOH$ (iii) $p-N{{O}_{2}}{{C}_{6}}{{H}_{4}}COOH$ (iv) $mN{{O}_{2}}{{C}_{6}}{{H}_{4}}COOH$ Which of the following orders is correct?

A) (i) > (ii) > (iii) > (iv)

B) (ii) > (iv) > (iii) > (i)

C) (ii) > (iv) > (i) > (iii)

D) (ii) > (iii) > (iv) > (i)

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• question_answer79) The compound formed on heating chlorobenzene with chloral in the presence of concentrated sulphuric acid is

A) gammexane

B) DDT

C) freon

D) hexachloroethane

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• question_answer80) The smog is essentially caused by the presence of

A) ${{O}_{2}}$and ${{O}_{3}}$

B) ${{O}_{2}}$a and${{N}_{3}}$

C) oxides of sulphur and nitrogen

D) ${{O}_{3}}$ and ${{N}_{2}}$

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• question_answer81) The radioisotope, tritium $(_{1}^{3}H)$ has a half-life of 12.3 yr. If the initial amount of tritium is 32 mg, how many milligrams of it would remain after 49.2 yr?

A) 4 mg

B) 8 mg

C) 1 mg

D) 2 mg

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• question_answer82) In this reaction $C{{H}_{3}}CHO+HCN\xrightarrow{{}}C{{H}_{3}}CH(OH)CN$ $\xrightarrow{\text{H}\text{.OH}}C{{H}_{3}}CH(OH)COOH$ an asymmetric centre is generated. The acid obtained would be

A) 50% D + 50% L-isomer

B) 20% D + 80% L-isomer

C) D-isomer

D) L-isomer

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• question_answer83) The method of zone refining of metals is based on the principle of

A) greater noble character of the solid metal than that of the impurity

B) greater solubility of the impurity in the molten state than in the solid

C) greater mobility of the pure metal than that of impurity

D) higher melting point of the impurity than that of the pure metal

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• question_answer84) The temperature dependence of rate constant $(k)$ of a chemical reaction is written in terms of Arrhenius equation,$k=A{{e}^{-E*/RT}}.$ Activation energy $({{E}^{*}})$of the reaction can be calculated by ploting

A) $\log \,k\,vs\frac{1}{T}$

B) $\log \,k\,vs\frac{1}{\log \,\,T}$

C) $l\,vs\,T$

D) $k\,vs\,\frac{1}{\log \,T}$

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• question_answer85) In a set of the given reactions, acetic acid yielded a product C. $C{{H}_{3}}COOH+PC{{l}_{5}}\xrightarrow{{}}A$ $\text{A}\xrightarrow[\text{anhy}\,\text{AlC}{{\text{l}}_{\text{3}}}]{{{\text{C}}_{\text{6}}}{{\text{H}}_{\text{6}}}}\text{B}\xrightarrow[\text{ether}]{{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\text{MgBr}}\text{C}$ Product C would be

A) $C{{H}_{3}}CH(OH){{C}_{6}}{{H}_{5}}$

B) $C{{H}_{3}}-\overset{{{C}_{2}}{{H}_{5}}}{\mathop{\overset{|}{\mathop{C}}\,}}\,(OH){{C}_{6}}{{H}_{5}}$

C) $C{{H}_{3}}CH(OH){{C}_{2}}{{H}_{5}}$

D) $C{{H}_{3}}CO{{C}_{6}}{{H}_{5}}$

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• question_answer86) Which one of the following compounds, is nota protonic acid?

A) $SO{{(OH)}_{2}}$

B) $S{{O}_{2}}{{(OH)}_{2}}$

C) $B{{(OH)}_{2}}$

D) $PO{{(OH)}_{3}}$

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• question_answer87) $\text{NaCl,}\,\text{NaBr}$and $\text{NaI}$mixture on heating with cone. ${{\text{H}}_{\text{2}}}\text{S}{{\text{O}}_{\text{4}}}$gives gases, respectively

A) $HCl,HBr,HI$

B) $HCl,B{{r}_{2}},{{I}_{2}}$

C) $C{{l}_{2}},B{{r}_{2}},{{I}_{2}}$

D) $C{{l}_{2}},HBr,HI$

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• question_answer88) The reaction between aniline and nitrous acid at low temperature yields

A) N-nitrosamine

B) diazonium salt

C) nitrile

D) amine-nitrite salt

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• question_answer89) The maximum number of molecules is present in

A) $15\,L\,$of ${{H}_{2}}$gas at STP

B) $5\,L\,$of ${{N}_{2}}$gas at STP

C) $0.5\,g\,$of ${{H}_{2}}$gas

D) $10\,g$of ${{O}_{2}}$gas

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• question_answer90) Ionic radii are

A) inversely proportional to effective nuclear charge

B) inversely proportional to square of effective nuclear charge

C) directly proportional to effective nuclear charge

D) directly proportional to square of effective nuclear charge

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• question_answer91) The radioactive isotope $_{\text{27}}^{\text{60}}\text{Co}$which is used in the treatment of cancer can be made by $(n,p)$ reaction. For this reaction the target nucleus is

A) $_{28}^{59}Ni$

B) $_{27}^{59}Co$

C) $_{28}^{60}Ni$

D) $_{27}^{60}Co$

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• question_answer92) The vapour pressure of two liquids P and Q are 80 and 60 Torr, respectively. The total vapour pressure of solution obtained by mixing 3 moles of P and 2 moles of Q would be

A) 140 Torr

B) 20 Torr

C) 68 Torr

D) 72 Torr

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• question_answer93) The energy of second Bohr orbit of the hydrogen atom is $-328\,\text{kJ}\,\text{mo}{{\text{l}}^{-}};$ hence the energy of fourth Bohr orbit would be

A) $~-41\,\text{kJ}\,\text{mo}{{\text{l}}^{-1}}$

B) $-1312\text{ kJ mo}{{\text{l}}^{-1}}$

C) $-164\text{ kJ mo}{{\text{l}}^{-1}}$

D) $~-82\text{ kJ mo}{{\text{l}}^{-1}}$

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• question_answer94) In van der Waals' equation of state of the gas law, the constant ?b? is a measure of

A) intermolecular repulsions

B) intermolecular attractions

C) volume occupied by the molecules

D) intermolecular collisions per unit volume

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• question_answer95) Which of the following is responsible for depletion of the ozone layer in the upper strata of the atmosphere?

A) Polyhalogens

B) Ferrocenes

C) Fullerenes

D) Freons

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• question_answer96) What is the correct IUPAC name of A) 4-methoxy-2-nitrobenzaldehyde

B) 4-formyl-3-nitro anisole

C) 4-methoxy-6-nitrobenzaldehyde

D) 2-formyl-5-methoxy nitrobenzene

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• question_answer97) Which of the following is anhydride of perchloric acid?

A) $\text{C}{{\text{l}}_{\text{2}}}{{\text{O}}_{\text{7}}}$

B) $\text{C}{{\text{l}}_{\text{2}}}{{\text{O}}_{5}}$

C) $\text{C}{{\text{l}}_{\text{2}}}{{\text{O}}_{3}}$

D) $HClO$

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• question_answer98) The concentration of ${{\text{H}}_{\text{2}}}{{\text{O}}_{\text{2}}}$solution of ?10 volume' is

A) 30%

B) 3%

C) 1%

D) 10%

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• question_answer99) The dipole moment of $\text{HBr}$is $\text{1}\text{.6}\times {{10}^{-30}}\,C-m$and inter-atomic spacing is$1\overset{\text{o}}{\mathop{\text{A}}}\,.$The % ionic character of $\text{HBr}$is

A) 7

B) 10

C) 15

D) 27

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• question_answer100) $Ca{{C}_{2}}+{{N}_{2}}\xrightarrow{{}}A,$product A is

A) $CaC{{N}_{2}}$

B) $CaC{{N}_{2}}$and C

C) $CaC{{N}_{2}}+{{N}_{2}}$

D) None of these

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• question_answer101) Which pigment involved in photoperiodic change in plants?

A) Phytochrome

B) Cytochrome

C) Chlorophyll

D) Anthocyanin

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• question_answer102) Blood vascular system of earthworm is

A) open type with Hb in RBC

B) open type with Hb in plasma

C) closed type with Hb in RBC

D) closed type with Hb in plasma

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• question_answer103) Succus entericus is

A) intestinal juice

B) gastric juice

C) bile juice

D) salivary juice

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• question_answer104) Synthesis of urea occurs in

A) kidney

B) liver

C) gallbladder

D) urinary bladder

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• question_answer105) A wastage process is

A) respiration

B) photosynthesis

C) photorespiration

D) movement

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• question_answer106) Lateral roots arise from

A) pericycle

B) cortex

C) endodermis

D) stele

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• question_answer107) Photosynthetic products translocated in the form of

A) glucose

B) sucrose

C) maltose

D) starch

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• question_answer108) Cell membrane controls

A) exocytosis

B) endocytosis

C) Both [a] and [b]

D) not controles movement of substances

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• question_answer109) Submerged hydrophytes shows

A) stomata

B) abundant air sacs

C) developed mechanical tissue

D) secondary growth

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• question_answer110) Which is not a reflex action?

A) Salivation

B) Eye opening and closing

C) Response to pinching pin in a frog leg

D) Sweating

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• question_answer111) Which is a correct pair of a pathogen and its vector?

A) Plasmodium and Anopheles

B) Plasmodium and Culex

C) Virus and Anopheles

D) Protozoan and Aedes

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• question_answer112) Vascular bundle in which two patches of phloem are present on both side of xylem is

A) collateral

B) bicollateral

C) concentric

D) radial

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• question_answer113) Presence of persistant calyx is a feature of family

A) Solanaceae

B) Gramineae

C) Malvaceae

D) Compositae

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• question_answer114) Amphimixis is

A) fusion of sperm with egg

B) fusion of pronucleus of sperm with of egg

C) no fusion

D) fusion of diploid cells

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• question_answer115) Addison of which elements in water, speed up the metamorphosis in frog tadpole larva?

A) ${{I}_{2}}$

B) $K$

C) Na

D) $Cl$

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• question_answer116) Steroid hormones work as

A) they enter into target cells and binds with specific receptor and activates specific genes to form protein

B) they binds to cell membrane

C) they catalyse formation of c-AMP

D) None of the above

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• question_answer117) In a double stranded DNA, the sequence of bases in one strand is AGCTAAGC. What is the complementary sequence on the other strand?

A) TCGATTCG

B) VCGAUUCG

C) AGCTAAGC

D) CAUTAUCG

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• question_answer118) Renal portal system is

A) present in all vertebrates

B) present in all chordates

C) absent in mammals

D) present in all mammals

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• question_answer119) Most diverse organism of an ecosystem is

A) producer

B) consumer

C) decomposer

D) carnivores

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• question_answer120) Which is correct for artery?

A) Thick walled in which blood flow at high pressure

B) Thin walled blood flow with low pressure

C) Thick walled and blood flow low pressure

D) None of the above

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• question_answer121) Which is correct for bacteria?

A) They have both cyclic and non-cyclic photo phosphorylation

B) They absorb light > 900 nm of wavelength

C) They release ${{\text{O}}_{\text{2}}}$ during photosynthesis

D) They use${{\text{H}}_{\text{2}}}\text{O}$ during photosynthesis

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• question_answer122) Which of the following is exhaustible but limited source of energy?

A) Nuclear fuels

B) Water energy

C) Fossil fuels

D) Solar energy

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• question_answer123) A pollutant can be best defined as it

A) has natural geochemical cycles

B) changes homeostasis of environment

C) disturb natural flora of a place

D) become stabilized in ecosystem forever

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• question_answer124) Disorder related with thyroid gland is

A) diabetes mellitus

B) hypercalcemia

C) osteoporosis

D) myxedema

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• question_answer125) ${{\text{C}}_{4}}-$pathway for $\text{C}{{\text{O}}_{\text{2}}}-$fixation was proposed by

A) Benson and associates

B) Arnon and associates

C) Rouhani et $al$

D) Hatch et $al,$

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• question_answer126) Stink gland is found in

A) 4th and 5th terga of cockroach

B) 5th and 6th terga of cockroach

C) 5th and 6th sterna of cockroach

D) 4th and 5th sterna of cockroach

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• question_answer127) First mammal occur in which era-period?

A) Permian-Palaeozoic

B) Triassic-Mesozoic

C) Tertiary-Coenozoic

D) None of the above

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• question_answer128) When temperature decreases oxyhaemoglobin curve will become

A) more steep

B) straight

C) parabola

D) All of the above

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• question_answer129) Regeneration of liver is

A) metamorphosis

B) repairative regeneration

C) epimorphosis

D) morphogenesis

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• question_answer130) Deamination occurs in

A) kidney

B) liver

C) nephron

D) Both [a] and [b]

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• question_answer131) Struggle for existence and survival of the fittest theories were given by

A) Wallace

B) Darwin

C) Lamarck

D) None of these

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• question_answer132) Digestion of protein is completed in

A) stomach

B) duodenum

C) ileum

D) Both [b] and [c]

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• question_answer133) Fight and flight hormone is

A) adrenaline

B) thyroxine

C) ADH

D) oxytocin

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• question_answer134) Myelin sheath is derived from

A) neuroglial cells

B) Schwann cells

C) nerve cells

D) All of these

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• question_answer135) Bidder's canal is found in

A) testes of frog

B) kidney of frog

C) kidney of rabbit

D) Both [a] and [c]

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• question_answer136) Keratinized dead layer of skin is made up of

A) stratified squamous

B) simple cuboidal

C) simple columnar

D) stratified columnar

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• question_answer137) Cristae are associated with which of the following?

A) Mitochondria

B) Cytoplasm

C) Protoplasm

D) Endoplasmic reticulum

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• question_answer138) Which of the following symbols are used for representing chromosome of birds?

A) ZZ-ZW

B) XX-XY

C) XO-XX

D) ZZ-WW

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• question_answer139) Genotypic ratio of a monohybrid cross is

A) 1:2:1

B) 3:1

C) 9:3:3:1

D) 1:1:1

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• question_answer140) Mesogamy is

A) fusion of male and female gametes

B) fusion of physiologically similar and morphologically different gametes

C) entry of pollen tube through integuments

D) None of the above

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• question_answer141) Most of the economically important fibre yielding plants belong to family

A) Malvaceae

B) Solanaceae

C) Cruciferae

D) Poaceae

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• question_answer142) Provirus is

A) a free virus

B) primitive virus

C) integrated viral genome

D) a free DNA

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• question_answer143) If root of a flowering plant has 24 chromosomes, then its gamete has how many chromosomes?

A) 24

B) 12

C) 4

D) 8

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• question_answer144) Nitrite is converted to nitrate by

A) Nitrosomonas

B) Nitrobacter

C) Pseudomonas

D) Clostridium

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• question_answer145) Collenchyma is

A) living and contains protoplasm

B) dead and hollow

C) dead and filled with reserve food

D) living and contains no reserve food

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• question_answer146) Gametophytic and sporophytic phases are independent in

A) pteridophyte

B) bryophyte

C) gymnosperms

D) phaeophytes

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• question_answer147) Number of archegonia in Cycas is

A) 8

B) 4

C) 1

D) 2

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• question_answer148) Extinction of a species in a food chain is compensated by

A) food chain

B) ecological pyramid

C) food web

D) None of the above

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• question_answer149) Pyramid of energy in aquatic ecosystem is

A) always upright

B) always inverted

C) bell-shaped

D) None of these

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• question_answer150) Photosynthesis is maximum in

A) green light

B) blue followed by red light

C) red followed by blue light

D) blue light

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