Current Affairs JEE Main & Advanced

Forces that keep the nucleons bound in the nucleus are called nuclear forces. (1) Nuclear forces are short range forces. These do not exist at large distances greater than \[{{10}^{-15}}\,m\]. (2) Nuclear forces are the strongest forces in nature. (3) These are attractive force and causes stability of the nucleus. (4) These forces are charge independent. (5) Nuclear forces are non-central force. (6) Nuclear forces are exchange forces : According to scientist Yukawa the nuclear force between the two nucleons is the result of the exchange of particles called mesons between the nucleons. \[\pi -\]mesons are of three types - Positive \[\pi \]meson \[({{\pi }^{+}})\], negative \[\pi \] meson \[({{\pi }^{-}})\], neutral \[\pi \] meson \[({{\pi }^{0}})\] The force between neutron and proton is due to exchange of charged meson between them i.e. \[p\to {{\pi }^{+}}+n,\,\,\,\,\,\,n\to p+{{\pi }^{-}}\] The forces between a pair of neutrons or a pair of protons are the result of the exchange of neutral meson \[({{\pi }^{0}})\] between them i.e. \[p\to p'+{{\pi }^{0}}\]   and    \[n\to n'+{{\pi }^{0}}\] Thus exchange of p meson between nucleons keeps the nucleons bound together. It is responsible for the nuclear forces. Dog-Bone analogy The above interactions can be explained with the dog bone analogy according to which we consider the two interacting nucleons to be two dogs having a common bone clenched in between their teeth very firmly. Each one of these dogs wants to take the bone and hence they cannot be separated easily. They seem to be bound to each other with a strong attractive force (which is the bone) though the dogs themselves are strong enemies. The meson plays the same role of the common bone in between two nucleons.

(1) Nuclear radius : Experimental results indicates that the nuclear radius is proportional to \[{{A}^{1/3}}\], where A is the mass number of nucleus i.e. \[R\propto {{A}^{1/3}}\]\[\Rightarrow \]\[R={{R}_{0}}{{A}^{1/3}}\], where \[{{R}_{0}}=1.2\times {{10}^{-15}}\,m=1.2\,\,fm\]. (2) Nuclear volume : The volume of nucleus is given by \[V=\frac{4}{3}\pi \,{{R}^{3}}=\frac{4}{3}\pi \,R_{0}^{3}A\,\,\Rightarrow V\propto A\] (3) Nuclear density : Mass per unit volume of a nucleus is called nuclear density. \[\text{Nuclear density}\,\text{(}\rho \,\text{) }=\,\frac{\text{Mass of nucleus}}{\text{Volume of nucleus}}=\frac{mA}{\frac{4}{3}\pi \,{{({{R}_{0}}{{A}^{1/3}})}^{3}}}\] where m = Average of mass of a nucleon (= mass of proton + mass of neutron \[=1.66\times {{10}^{-27}}\,kg\]) and \[mA=\]Mass of nucleus \[\Rightarrow \]\[\rho =\frac{3m}{4\pi R_{0}^{3}}=2.38\times {{10}^{17}}kg/{{m}^{3}}\]    

The nuclei have been classified on the basis of the number of protons (atomic number) or the total number of nucleons (mass number) as follows (1) Isotopes : The atoms of element having same atomic number but different mass number are called isotopes. All isotopes have the same chemical properties. The isotopes of some elements are the following \[_{1}{{H}^{1}},\,{{\,}_{1}}{{H}^{2}},\,{{\,}_{1}}{{H}^{3}}\] \[_{8}{{O}^{16}},\,{{\,}_{8}}{{O}^{17}},\,{{\,}_{8}}{{O}^{18}}\] \[_{2}H{{e}^{3}},\,{{\,}_{2}}H{{e}^{4}}\]  \[_{17}C{{l}^{35}},\,{{\,}_{17}}C{{l}^{37}}\]    \[_{92}{{U}^{235}},\,{{\,}_{92}}{{U}^{238}}\] (2) Isobars : The nuclei which have the same mass number (A) but different atomic number (Z) are called isobars. Isobars occupy different positions in periodic table so all isobars have different chemical properties. Some of the examples of isobars are \[_{1}{{H}^{3}}\,\text{and }{{\,}_{2}}H{{e}^{3}},\,\,\,\,\,\,{{\,}_{6}}{{C}^{14}}\,\text{and}{{\,}_{\text{7}}}{{N}^{14}},\,{{\,}_{8}}{{O}^{17}}\,\text{and }{{\,}_{9}}{{F}^{17}}\] (3) Isotones : The nuclei having equal number of neutrons are called isotones. For them both the atomic number (Z) and mass number (A) are different, but the value of (A - Z) is same. Some examples are \[_{4}B{{e}^{9}}\,\text{and}{{\,}_{5}}{{B}^{10}},{{\,}_{6}}{{C}^{13}}\,\text{and}{{\,}_{7}}{{N}^{14}},{{\,}_{8}}{{O}^{18}}\text{ and}{{\text{ }}_{9}}{{F}^{19}}\] \[{{\,}_{3}}L{{i}^{7}}\,\text{and }{{\,}_{\text{4}}}B{{e}^{8}},{{\,}_{1}}{{H}^{3}}\,\text{and}{{\,}_{\text{2}}}H{{e}^{4}}\] (4) Mirror nuclei : Nuclei having the same mass number A but with the proton number (Z) and neutron number (A ? Z) interchanged (or whose atomic number differ by 1) are called mirror nuclei for example. \[_{1}{{H}^{3}}\,\text{and}{{\,}_{\text{2}}}H{{e}^{3}},\,{{\,}_{3}}L{{i}^{7}}\,\text{and}{{\text{ }}_{\text{4}}}B{{e}^{7}}\]

Fast neutrons can be converted into slow neutrons by certain materials called moderator's (Paraffin wax, heavy water, graphite) when fast moving neutrons pass through a moderator, they collide with the molecules of the moderator, as a result of this, the energy of moving neutron decreases while that of the molecules of the moderator increases. After sometime they both attains same energy. The neutrons are then in thermal equilibrium with the molecules of the moderator and are called thermal neutrons. Energy of thermal neutron is about 0.025 eV and speed is about 2.2 km/s.

Neutron is a fundamental particle which is essential constituent of all nuclei except that of hydrogen atom. It was discovered by Chadwick. A free neutron outside the nucleus is unstable and decays into proton and electron.  \[_{0}{{n}^{1}}\,\,\to \,\,\underset{\text{Proton}}{\mathop{_{1}{{H}^{1}}}}\,\,\,+\,\,\underset{\text{Electron}}{\mathop{_{-1}{{\beta }^{0}}}}\,\,\,+\,\,\underset{\text{Antinutrino}}{\mathop{{\bar{\nu }}}}\,\] (1) The charge of neutron : It is neutral (2) The mass of neutron : \[1.6750\times {{10}^{-27}}\,kg\] (3) It's spin angular momentum : \[\frac{1}{2}\times \left( \frac{h}{2\pi } \right)\,J\text{-}s\] (4) It's magnetic moment : \[9.57\times {{10}^{-27}}\,J/Tesla\] (5) It's half life : 12 minutes (6) Penetration power : High (7) Types : Neutrons are of two types slow neutron and fast neutron, both are fully capable of penetrating a nucleus and causing artificial disintegration.

(1) Rutherford's \[\alpha -\]scattering experiment established that the mass of atom is concentrated with small positively charged region at the centre which is called 'nucleus'. (2) The stability or instability of a particular nucleus is determined by the competition between the attractive nuclear force among the protons and neutrons and the repulsive electrical interactions among the protons. Unstable nuclei decay, transforming themselves spontaneously into other structure by a variety of decay processes. (3) We could not survive without the \[3.90\times {{10}^{26}}\] watt output of one near by fusion reactor, our sun. (4) Nuclei are made up of proton and neutron. The number of protons in a nucleus (called the atomic number or proton number) is represented by the symbol Z. The number of neutrons (neutron number) is represented by N. The total number of neutrons and protons in a nucleus is called it's mass number A so \[A=Z+N\]. (5) Neutrons and proton, when described collectively are called nucleons. A single nuclear species having specific values of both Z and N is called a nuclide. (6) Nuclides are represented as \[_{Z}{{X}^{A}};\] where X denotes the chemical symbol of the element.

The distribution of electrons in different orbitals of an atom is called the electronic configuration of the atom. The filling of electrons in orbitals is governed by the following rules. (1) Pauli's exclusion principle : "It states that no two electrons in an atom can have all the four quantum number (n, l, \[{{m}_{l}}\] and \[{{m}_{s}}\]) the same." It means each quantum state of an electron must have a different set of quantum numbers n, l, \[{{m}_{l}}\] and \[{{m}_{s}}\]. This principle sets an upper limit on the number of electrons that can occupy a shell. \[{{N}_{\max }}\] in one shell \[=2{{n}^{2}};\] Thus \[{{N}_{\max }}\] in K, L, M, N ?. shells are 2, 8, 18, 32, (2) Aufbau principle : Electrons enter the orbitals of lowest energy first. As a general rule, a new electron enters an empty orbital for which \[(n+1)\] is minimum. In case the value \[(n+l)\] is equal for two orbitals, the one with lower value of n is filled first. Thus the electrons are filled in subshells in the following order (memorize) 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p, .... (3) Hund's Rule : When electrons are added to a subshell where more than one orbital of the same energy is available, their spins remain parallel. They occupy different orbitals until each one of them has at least one electron. Pairing starts only when all orbitals are filled up. Pairing takes place only after filling 3, 5 and 7 electrons in p, d and f orbitals, respectively.

An atom contains large number of shells and subshells. These are distinguished from one another on the basis of their size, shape and orientation (direction) in space. The parameters are expressed in terms of different numbers called quantum number. Quantum numbers may be defined as a set of four number with the help of which we can get complete information about all the electrons in an atom. It tells us the address of the electron i.e. location, energy, the type of orbital occupied and orientation of that orbital. (1) Principal Quantum number (n) : This quantum number determines the main energy level or shell in which the electron is present. The average distance of the electron from the nucleus and the energy of the electron depends on it. \[{{E}_{n}}\propto \frac{1}{{{n}^{2}}}\]  and   \[{{r}_{n}}\propto {{n}^{2}}\] (in H-atom) The principal quantum number takes whole number values, n = 1, 2, 3, 4,... \[\infty \] (2) Orbital quantum number (l) or azimuthal quantum number \[(l)\] : This represents the number of subshells present in the main shell. These subsidiary orbits within a shell will be denoted as 1, 2, 3, 4 ? or s, p, d, f ... This tells the shape of the subshells. The orbital angular momentum of the electron is given as \[L=\sqrt{l(l+1)}\,\frac{h}{2\pi }\]  (for a particular value of n).   For a given value of n the possible values of \[l\] are \[l\] = 0, 1, 2, ... upto  \[(n-1)\] (3) Magnetic quantum number \[({{m}_{l}})\] : An electron due to it's angular motion around the nucleus generates an electric field. This electric field is expected to produce a magnetic field. Under the influence of external magnetic field, the electrons of a subshell can orient themselves in certain preferred regions of space around the nucleus called orbitals. The magnetic quantum number determines the number of preferred orientations of the electron present in a subshell. The angular momentum quantum number m can assume all integral value between \[-l\] to \[+l\] including zero. Thus \[{{m}_{l}}\] can be \[-1,\,\,0,\,\,+\,\,1\] for \[l=1\]. Total values of \[{{m}_{l}}\] associated with a particular value of \[l\] is given by \[(2l+1)\]. (4) Spin (magnetic) quantum number \[({{m}_{s}})\] : An electron in atom not only revolves around the nucleus but also spins about its own axis. Since an electron can spin either in clockwise direction or in anticlockwise direction. Therefore for any particular value of magnetic quantum number, spin quantum number can have two values, i.e. \[{{m}_{s}}=\frac{1}{2}\] (Spin up)  or \[{{m}_{s}}=-\frac{1}{2}\]  (Spin down) This quantum number helps to explain the magnetic properties of the substance. Quantum states of the hydrogen atom

When hydrogen atom is excited, it returns to its normal unexcited (or ground state) state by emitting the energy it had absorbed earlier. This energy is given out by the atom in the form of radiations of different wavelengths as the electron jumps down from a higher to a lower orbit. Transition from different orbits cause different wavelengths, these constitute spectral series which are characteristic of the atom emitting them. When observed through a spectroscope, these radiations are imaged as sharp and straight vertical lines of a single colour. The spectral lines arising from the transition of electron forms a spectra series. (1) Mainly there are five series and each series is named after it's discover as Lymen series, Balmer series, Paschen series, Bracket series and Pfund series. (2) According to the Bohr's theory the wavelength of the radiations emitted from hydrogen atom is given by \[\frac{1}{\lambda }=R\,\left[ \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} \right]\]\[\Rightarrow \]\[\lambda =\frac{n_{1}^{2}n_{2}^{2}}{(n_{2}^{2}-n_{1}^{2})R}=\frac{n_{1}^{2}}{\left( 1-\frac{n_{1}^{2}}{n_{2}^{2}} \right)R}\] where \[{{n}_{2}}=\]outer orbit (electron jumps from this orbit), \[{{n}_{1}}=\] inner orbit (electron falls in this orbit) (3) First line of the series is called first member, for this line wavelength is maximum \[({{\lambda }_{\max }})\] For maximum wavelength if \[{{n}_{1}}=n\] then \[{{n}_{2}}=n+1\] So \[{{\lambda }_{\max }}=\frac{{{n}^{2}}{{(n+1)}^{2}}}{(2n+1)R}\] (4) Last line of the series is called series limit, for this line wavelength is minimum \[({{\lambda }_{\min }})\] For minimum wavelength \[{{n}_{2}}=\infty ,\,{{n}_{1}}=n\] So \[{{\lambda }_{\min }}=\frac{{{n}^{2}}}{R}\] (5) The ratio of first member and series limit can be calculated as \[\frac{{{\lambda }_{\max }}}{{{\lambda }_{\min }}}=\frac{{{(n+1)}^{2}}}{(2n+1)}\] Different spectral series
Spectral series Transition \[{{\lambda }_{\max }}\] \[{{\lambda }_{\min }}\] \[\frac{{{\lambda }_{max}}}{{{\lambda }_{min}}}\] Region
1. Lymen series \[{{n}_{2}}=\]  2, 3, 4 ... \[\infty \] \[{{n}_{1}}=1\]   more...
When an electron makes transition from higher energy level having energy \[{{E}_{2}}({{n}_{2}})\] to a lower energy level having energy \[{{E}_{1}}({{n}_{1}})\] then a photon of frequency n is emitted (1) Energy of emitted radiation \[\Delta E={{E}_{2}}-{{E}_{1}}\]\[=\frac{-Rc\,h\,{{Z}^{2}}}{n_{2}^{2}}-\left( -\frac{Rch\,{{Z}^{2}}}{n_{1}^{2}} \right)\] \[=13.6{{Z}^{2}}\left( \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} \right)\] (2) Frequency of emitted radiation                         \[\Delta E=h\nu \]\[\Rightarrow \]\[\nu =\frac{\Delta E}{h}=\frac{{{E}_{2}}-{{E}_{1}}}{h}=Rc\,{{Z}^{2}}\,\left( \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} \right)\] (3) Wave number/wavelength Wave number is the number of waves in unit length \[\bar{\nu }=\frac{1}{\lambda }=\frac{\nu }{c}\]\[\Rightarrow \frac{1}{\lambda }=R{{Z}^{2}}\left( \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} \right)=\frac{13.6{{Z}^{2}}}{hc}\left( \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} \right)\] (4) Number of spectral lines : If an electron jumps from higher energy orbit to lower energy orbit it emits raidations with various spectral lines. If electron falls from orbit \[{{n}_{2}}\] to \[{{n}_{1}}\] then the number of spectral lines emitted is given by \[{{N}_{E}}=\frac{({{n}_{2}}-{{n}_{1}}+1)({{n}_{2}}-{{n}_{1}})}{2}\] If electron falls from \[{{n}^{th}}\] orbit to ground state (i.e. \[{{n}_{2}}=n\] and \[{{n}_{1}}=1\]) then number of spectral lines emitted \[{{N}_{E}}=\frac{n\,(n-1)}{2}\] (5) Recoiling of an atom : Due to the transition of electron, photon is emitted and the atom is recoiled Recoil momentum of atom = momentum of photon \[=\frac{h}{\lambda }=hR{{Z}^{2}}\,\left( \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} \right)\] Also recoil energy of atom \[=\frac{{{p}^{2}}}{2m}\]\[=\frac{{{h}^{2}}}{2m{{\lambda }^{2}}}\]   (where \[m=\] mass of recoil atom)


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